Carbon monoxide;1-(2-ethenylphenyl)propan-1-one;ruthenium;triphenylphosphane | 201863-18-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Carbon monoxide;1-(2-ethenylphenyl)propan-1-one;ruthenium;triphenylphosphane
• CAS: 201863-18-5
• 化学式: C₄₈H₄₂O₂P₂Ru
• 分子量: 813.878
• InChiKey: AYXIYVANVXKAHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.77
• 重原子数：
  53
• 可旋转键数：
  9
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  18.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  RuH₂(CO)(PPh₃)₃ 、 1-(2-vinylphenyl)propan-1-one 在 styrene 作用下， 以 甲苯 为溶剂， 生成 Carbon monoxide;1-(2-ethenylphenyl)propan-1-one;ruthenium;triphenylphosphane
  参考文献：
  名称：

  Preparation, Characterization, and X-ray Structure of the 1:1 Complex of o-Acetylstyrene and Carbonylbis(triphenylphosphine)ruthenium. A New Catalyst for the Copolymerization of Acetophenone and 1,3-Divinyltetramethyldisiloxane

  摘要：

  Treatment of dihydridocarbonyltris(triphenylphosphine)ruthenium with a stoichiometric amount of styrene, followed by addition of o-acetylstyrene leads to a 1:1 complex of o-acetylstyrene and carbonylbis(triphenylphosphine)ruthenium. This species has been fully characterized and its structure determined by X-ray crystallography. This 1:1 complex is able to-catalyze the copolymerization of acetophenone and 1,3-divinyltetramethyldisiloxane.

  DOI：

  10.1021/om9708541