3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol | 219607-76-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol
• 英文别名: (3-Hydroxy-2-phenylselanylpropyl) 3-chlorobenzoate
• CAS: 219607-76-8
• 化学式: C₁₆H₁₅ClO₃Se
• 分子量: 369.706
• InChiKey: HJYIXTOPSUXHLH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.31
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol 在 水 作用下， 生成 2-(phenylselenyl)-1,3-propanediol
  参考文献：
  名称：

  Formation of 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)-3-(phenylseleno)propan-1-ol from a reaction of allyl phenyl selenide withm-chloroperoxybenzoic acid

  摘要：

  Oxidation of allyl phenyl selenide with m-chloroperoxybenzoic acid unexpectedly afforded two compounds, the structures of which were determined as 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)3-(phenylseleno)propan-1-ol. Structure determination of the products is described and the possible mechanisms are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)02020-6
• 作为产物：
  描述：

  烯丙基苯基硒 、 间氯过氧苯甲酸 以 二氯甲烷 为溶剂， 反应 2.0h， 以47%的产率得到3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol
  参考文献：
  名称：

  Formation of 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)-3-(phenylseleno)propan-1-ol from a reaction of allyl phenyl selenide withm-chloroperoxybenzoic acid

  摘要：

  Oxidation of allyl phenyl selenide with m-chloroperoxybenzoic acid unexpectedly afforded two compounds, the structures of which were determined as 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)3-(phenylseleno)propan-1-ol. Structure determination of the products is described and the possible mechanisms are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)02020-6

文献信息

• Formation of 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)-3-(phenylseleno)propan-1-ol from a reaction of allyl phenyl selenide withm-chloroperoxybenzoic acid
  作者：Takanori Hirose、Nobuhiro Morita、Mitsuhiro Asakura、Keisuke Kitahara、Shinji Toyota、Michinori O¯ki

  DOI：10.1016/s0040-4039(98)02020-6

  日期：1998.11

  Oxidation of allyl phenyl selenide with m-chloroperoxybenzoic acid unexpectedly afforded two compounds, the structures of which were determined as 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)3-(phenylseleno)propan-1-ol. Structure determination of the products is described and the possible mechanisms are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.