甲基苯基硫酸盐 | 66735-55-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 中文名称: 甲基苯基硫酸盐
• 英文名称: Methyl-phenyl-sulfat
• 英文别名: phenyl methyl sulfate；Phe-nylmethylsulfate；methyl phenyl sulfate
• CAS: 66735-55-5
• 化学式: C₇H₈O₄S
• 分子量: 188.204
• InChiKey: KJNZDMKPARNMTH-UHFFFAOYSA-N

物化性质

• 沸点：
  287.7±13.0 °C(Predicted)
• 密度：
  1.336±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  61
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲基苯基硫酸盐 在 三氧化硫 作用下， 以 硝基甲烷-d3 为溶剂， 反应 0.5h， 生成 4-Methoxysulfonyloxy-benzenesulfonic acid
  参考文献：
  名称：

  关于苯基硫酸氢盐在酚的磺化中的作用。苯酚，茴香醚，甲基苯基硫酸酯，2- halogenophenols，用2,6-二甲基苯胺的一系列苯基甲磺酸盐一起和它的磺化Ñ甲基磺酰基衍生物†往最‡

  摘要：

  在25℃下用浓硫酸水溶液磺化甲基苯基硫酸酯（4），得到4-磺酸。然后该初始产物分解得到苯酚-4-磺酸，随后将其磺化为苯酚-2,4-二磺酸。从在93.2％H 2 SO 4中将甲磺酸苯基酯（3）和（4）磺化所获得的一级系数，对于磺酸浓度为H 2 S 2 O 7的酸浓度，其σp +值OSO 2 Me和OSO 2已确定OMe取代基分别为0.40和0.46。2-氯苯基（10）和2-甲基苯基甲磺酸盐（14）在2.0 °C下在硝基甲烷中用2.0当量的SO 3磺化产生4-磺酸作为排他的产物，而2-甲氧基苯基甲烷磺酸盐（13），在相同条件下，仅形成5-磺酸。

  DOI：

  10.1002/recl.19881071204
• 作为产物：
  描述：

  benzenediazonium tetrafluoroborate 、 硫酸二甲酯 生成 甲基苯基硫酸盐
  参考文献：
  名称：

  芳氧基亚砜鎓盐的合成

  摘要：

  芳氧磺鎓盐（四氟硼酸盐和六氟磷酸盐）是通过在过量的各种含磺酰基的化合物（包括砜和芳基酯，以及链烷烃和芳烃磺酸的烷基化酰胺）中分解芳构氮鎓盐而制得的。

  DOI：

  10.1039/j39700000682

文献信息

• METHODS OF SYNTHESIZING A POLYNUCLEOTIDE ARRAY USING PHOTOACTIVATED AGENTS
  申请人：Vibrant Holdings, LLC

  公开号：US20210380629A1

  公开（公告）日：2021-12-09

  Described herein are methods for the synthesis of DNA polynucleotides and polynucleotides, as well as methods for their deprotection and methods for the use of said compounds and compositions comprising said compounds. In particular, such compounds and compositions comprising them are used in methods for light-directed synthesis of DNA microarrays.

  本文描述了合成DNA多核苷酸和多核苷酸的方法，以及它们的去保护方法、使用这些化合物的方法和包含这些化合物的组合物的方法。特别是，这些化合物和包含它们的组合物用于DNA微阵列的光导向合成方法。
• Conductive polymer and solid electrolytic capacitor using same
  申请人：Tozawa Masaaki

  公开号：US20060223976A1

  公开（公告）日：2006-10-05

  The conductive polymer of the present invention is prepared by means of oxidation polymerization. On the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is coated. Alternatively, in the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is included. The conductive polymer of the present invention is excellent in the conductivity, heat resistance and moisture resistance. By using it as a solid electrolyte, a reliable solid electrolytic capacitor can be prepared which is unlikely to decrease the properties when being kept in a hot and humid condition.

  本发明的导电聚合物是通过氧化聚合制备的。在导电聚合物的基质上，至少涂覆了一种由有机磺酸阴离子和过渡金属以外的阳离子形成的有机磺酸盐。或者，在导电聚合物的基质中，至少包含了一种由有机磺酸阴离子和过渡金属以外的阳离子形成的有机磺酸盐。本发明的导电聚合物具有优异的导电性、耐热性和耐潮湿性。将其用作固体电解质，可以制备出可靠的固态电解电容器，在热湿条件下使用时不太可能降低其性能。
• Conductive polymer and solid electrolytic capacitor using the same
  申请人：Tozawa Masaaki

  公开号：US20080135810A1

  公开（公告）日：2008-06-12

  The conductive polymer of the present invention is prepared by means of oxidation polymerization. On the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is coated. Alternatively, in the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is included. The conductive polymer of the present invention is excellent in the conductivity, heat resistance and moisture resistance. By using it as a solid electrolyte, a reliable solid electrolytic capacitor can be prepared which is unlikely to decrease the properties when being kept in a hot and humid condition.

  本发明的导电聚合物是通过氧化聚合制备的。在导电聚合物的基质上，至少涂覆了一种由有机磺酸的阴离子和过渡金属以外的阳离子形成的有机磺酸盐。或者，在导电聚合物的基质中，至少包含了一种由有机磺酸的阴离子和过渡金属以外的阳离子形成的有机磺酸盐。本发明的导电聚合物具有优异的导电性、耐热性和耐潮湿性。通过将其用作固态电解质，可以制备出可靠的固态电解电容器，即使在高温高湿的条件下也不太可能降低其性能。
• CONDUCTIVE POLYMER AND SOLID ELECTROLYTIC CAPACITOR USING SAME
  申请人：Tayca Corporation

  公开号：EP1661931A1

  公开（公告）日：2006-05-31

  The conductive polymer of the present invention is prepared by means of oxidation polymerization. On the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is coated. Alternatively, in the matrix of the conductive polymer, at least one organic sulfonate formed by an anion of an organic sulfonic acid and a cation of other than transition metals is included. The conductive polymer of the present invention is excellent in the conductivity, heat resistance and moisture resistance. By using it as a solid electrolyte, a reliable solid electrolytic capacitor can be prepared which is unlikely to decrease the properties when being kept in a hot and humid condition.

  本发明的导电聚合物是通过氧化聚合法制备的。在导电聚合物的基体上，涂覆至少一种由有机磺酸的阴离子和过渡金属以外的阳离子形成的有机磺酸盐。或者，在导电聚合物的基体中，包含至少一种由有机磺酸的阴离子和过渡金属以外的阳离子形成的有机磺酸盐。本发明的导电聚合物具有优异的导电性、耐热性和防潮性。将其用作固态电解质，可以制备出可靠的固态电解电容器，在湿热条件下也不会降低其性能。
• OXIDANT/DOPANT SOLUTION FOR PRODUCING CONDUCTIVE POLYMER, CONDUCTIVE POLYMER AND SOLID ELECTROLYTIC CAPACITOR
  申请人：Tayca Corporation

  公开号：EP2479201A1

  公开（公告）日：2012-07-25

  There is provided an oxidant and dopant which can produce a conductive polymer. The conductive polymer can be used in a solid electrolyte capacitor as solid electrolyte. The solid electrolyte capacitor can be provided with improved breakdown voltage and voltage resistance, as well as less generation of the defects due to leak current. There is provided an oxidant and dopant solution for conductive polymer production including an oxidant and dopant for an organic ferric sulfonate, and an alcohol with a carbon number of 1 to 4. The oxidant and dopant solution further includes a compound with a glycidyl group, or its ring-opened compound. Faborably, a polyalcohol is further added. Using the oxidant and dopant solution, a thiophene or its derivative is subject to an oxidation polymerization to prepare a conductive polymer, which can be used as solid electrolyte of a solid electrolyte capacitor.

  提供了一种氧化剂和掺杂剂，可生成导电聚合物。该导电聚合物可用作固体电解质电容器的固体电解质。固体电解质电容器的击穿电压和耐压性能得到改善，泄漏电流导致的缺陷也会减少。本发明提供了一种用于导电聚合物生产的氧化剂和掺杂剂溶液，其中包括一种有机磺酸铁氧化剂和掺杂剂，以及一种碳原子数为 1 至 4 的醇，氧化剂和掺杂剂溶液还包括一种具有缩水甘油基的化合物或其环开化合物。当然，还可以进一步加入多元醇。利用氧化剂和掺杂剂溶液，对噻吩或其衍生物进行氧化聚合，制备出导电聚合物，该聚合物可用作固体电解质电容器的固体电解质。