1,3-Cyclohexanedione, 5,5-dimethyl-2-[(4-nitrophenyl)methylene]- | 288155-33-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-Cyclohexanedione, 5,5-dimethyl-2-[(4-nitrophenyl)methylene]-
• 英文别名: 5,5-dimethyl-2-[(4-nitrophenyl)methylidene]cyclohexane-1,3-dione
• CAS: 288155-33-9
• 化学式: C₁₅H₁₅NO₄
• 分子量: 273.288
• InChiKey: BOXFKQNPDYIMFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  80
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-Cyclohexanedione, 5,5-dimethyl-2-[(4-nitrophenyl)methylene]- 在 劳森试剂 作用下， 以 乙腈 为溶剂， 以78%的产率得到5,5-dimethyl-2-[(4-nitrophenyl)methylidene]cyclohexane-1,3-dithione
  参考文献：
  名称：

  STUDIES ON ORGANOPHOSPHORUS COMPOUNDS V^1-4. REACTION OF 2,4-BIS(4-METHOXYPHENYL)-1,3,2,4-DITHIA DIPHOSPHETANE-2,4-DISULFIDE WITH CYCLIC AND HETEROCYCLIC KETONES

  摘要：

  Cyclic ketones 2 and 8a,b reacted with Lawesson's reagent (1) in different molar ratios to give the oxathiaphosphole (4), the disulfide 7 and the dithiones 9a,b. N-Methyl barbituric acid (10b) reacted with LR to produce the enethiole 11 and the sulfide 12. Pyrazolone derivatives 13 and 17 reacted with LR in different molar ratios to form the corresponding products 15, 16 and 19. Rohdanine (20) reacted with LR to give the enethiole 22 and the disulfide 23.

  DOI：

  10.1080/10426500008042100
• 作为产物：
  描述：

  对硝基苯甲醛 在 三乙烯二胺 作用下， 以 水 为溶剂， 生成 1,3-Cyclohexanedione, 5,5-dimethyl-2-[(4-nitrophenyl)methylene]-
  参考文献：
  名称：

  Synthesis of Arylmethylene-bis(3-hydroxy-5,5-dimethylcyclohex-2-en-1-one) Derivatives and Their Effect on Tyrosinase Activity

  摘要：

  DOI：

  10.5562/cca3857

文献信息

• STUDIES ON ORGANOPHOSPHORUS COMPOUNDS V^1-4. REACTION OF 2,4-BIS(4-METHOXYPHENYL)-1,3,2,4-DITHIA DIPHOSPHETANE-2,4-DISULFIDE WITH CYCLIC AND HETEROCYCLIC KETONES
  作者：Nadia Ragab Mohamed

  DOI：10.1080/10426500008042100

  日期：2000.6.1

  Cyclic ketones 2 and 8a,b reacted with Lawesson's reagent (1) in different molar ratios to give the oxathiaphosphole (4), the disulfide 7 and the dithiones 9a,b. N-Methyl barbituric acid (10b) reacted with LR to produce the enethiole 11 and the sulfide 12. Pyrazolone derivatives 13 and 17 reacted with LR in different molar ratios to form the corresponding products 15, 16 and 19. Rohdanine (20) reacted with LR to give the enethiole 22 and the disulfide 23.
• Synthesis of Arylmethylene-bis(3-hydroxy-5,5-dimethylcyclohex-2-en-1-one) Derivatives and Their Effect on Tyrosinase Activity
  作者：Elma Veljović、Hrvoje Rimac、Mirsada Salihović、Selma Špirtović-Halilović、Amar Osmanović、Nejra Kovač、Elizabeta Kiršek、Enida Članjak-Kudra、Dijana Špirtović、Mirza Bojić

  DOI：10.5562/cca3857

  日期：——