2-Pyridin-2-ylpyridine;ruthenium(2+);chloride | 182047-71-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-Pyridin-2-ylpyridine;ruthenium(2+);chloride
• CAS: 182047-71-8
• 化学式: C₂₀H₁₆ClN₄Ru
• 分子量: 448.897
• InChiKey: JMOGQVUFMOAHMH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.29
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  tris(2,2'-bipyridyl)ruthenium dichloride 、 乙腈 以 乙腈 为溶剂， 生成 bis(2,2'-bipyridyl)chloro(acetonitrile)ruthenium(II)(1+) 、 2-Pyridin-2-ylpyridine;ruthenium(2+);chloride
  参考文献：
  名称：

  Online Mass Analysis of Reaction Products by Electrospray Ionization. Photosubstitution of Ruthenium(II) Diimine Complexes

  摘要：

  The first observation of photosubstitution products in electrospray mass spectra is reported. The solvent-coordinated Ru(II) complex ions created by photodissociation of Ru(2,2'-bipyrazine)(3)Cl-2, Ru(2,2'-bipyridine)(3)X(2) (X = Cl- and ClO4-), and the related complexes in acetonitrile solution were directly detected by on-line electrospray mass spectrometry. The mass spectra were well explained in terms of coordinating ability of counterions and solvent. Collision-induced dissociation in the gas phase was an important process particularly for interpretation of photoproducts such as weakly-bound solvent-coordinated complexes. It was found that the electrospray technique, combined with a flowing photoreaction cell, can potentially be used to identify photoproducts or intermediates.

  DOI：

  10.1021/ic00119a007

文献信息

• Online Mass Analysis of Reaction Products by Electrospray Ionization. Photosubstitution of Ruthenium(II) Diimine Complexes
  作者：Ryuichi Arakawa、Jian Lu、Akio Yoshimura、Koichi Nozaki、Takeshi Ohno、Hidekazu Doe、Takekiyo Matsuo

  DOI：10.1021/ic00119a007

  日期：1995.7

  The first observation of photosubstitution products in electrospray mass spectra is reported. The solvent-coordinated Ru(II) complex ions created by photodissociation of Ru(2,2'-bipyrazine)(3)Cl-2, Ru(2,2'-bipyridine)(3)X(2) (X = Cl- and ClO4-), and the related complexes in acetonitrile solution were directly detected by on-line electrospray mass spectrometry. The mass spectra were well explained in terms of coordinating ability of counterions and solvent. Collision-induced dissociation in the gas phase was an important process particularly for interpretation of photoproducts such as weakly-bound solvent-coordinated complexes. It was found that the electrospray technique, combined with a flowing photoreaction cell, can potentially be used to identify photoproducts or intermediates.