1-(2-chlorobenzoyl)-2,2-dimethyl-2-(2-propen-1-yl)hydrazinium bromide | 650638-42-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(2-chlorobenzoyl)-2,2-dimethyl-2-(2-propen-1-yl)hydrazinium bromide
• 英文别名: 2-(2-Chlorobenzoyl)-1,1-dimethyl-1-(prop-2-en-1-yl)hydrazin-1-ium bromide；[(2-chlorobenzoyl)amino]-dimethyl-prop-2-enylazanium;bromide
• CAS: 650638-42-9
• 化学式: Br*C₁₂H₁₆ClN₂O
• 分子量: 319.629
• InChiKey: VZZBSXHNTKMMNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.75
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-(2-chlorobenzoyl)-2,2-dimethylhydrazine 、 3-溴丙烯 以 乙腈 为溶剂， 以75%的产率得到1-(2-chlorobenzoyl)-2,2-dimethyl-2-(2-propen-1-yl)hydrazinium bromide
  参考文献：
  名称：

  摘要：

  1-Aroyl-2,2-dimcthylhydrazines react with propargyl and allyl bromides to form, respectively, 1,1-dimethyl-1-(2-propyn-1-yl)- and 1,1-dimethyl-1-(2-propen-1-yl)-2-aroylhydrazinium bromides. Treatment of these compounds with an NaOH solution yielded, respectively, N-[dimethyl(2-propyn-1-yl)ammonio]- and N-[dimethyl(2-propen-1-yl)ammonio]aroylimides.1-Aroyl-2,2-dimethylhydrazines react with propargyl and allyl bromides to form, respectively, 1,1-dimethyl-1-(2-propyn-1-yl)- and 1,1-dimethyl-]-(2-propen-1-yl)-2-aroylhydrazinium bromides. Treatment of these compounds with an NaOH solution yielded, respectively, N-[dimethyl(2-propyn-1-yl)ammonio]- and N-[dimethyl(2-propen-1-yl)ammonio]aroylimides.

  DOI：

  10.1023/a:1025644620981

文献信息

• ——
  作者：A. S. Nakhmanovich、T. V. Nizovtseva、R. V. Karnaukhova、T. N. Komarova、A. I. Albanov、V. A. Lopyrev

  DOI：10.1023/a:1025644620981

  日期：——

  1-Aroyl-2,2-dimcthylhydrazines react with propargyl and allyl bromides to form, respectively, 1,1-dimethyl-1-(2-propyn-1-yl)- and 1,1-dimethyl-1-(2-propen-1-yl)-2-aroylhydrazinium bromides. Treatment of these compounds with an NaOH solution yielded, respectively, N-[dimethyl(2-propyn-1-yl)ammonio]- and N-[dimethyl(2-propen-1-yl)ammonio]aroylimides.1-Aroyl-2,2-dimethylhydrazines react with propargyl and allyl bromides to form, respectively, 1,1-dimethyl-1-(2-propyn-1-yl)- and 1,1-dimethyl-]-(2-propen-1-yl)-2-aroylhydrazinium bromides. Treatment of these compounds with an NaOH solution yielded, respectively, N-[dimethyl(2-propyn-1-yl)ammonio]- and N-[dimethyl(2-propen-1-yl)ammonio]aroylimides.