4,4'-Dimethyl-6,6'-bis-piperidin-1-ylmethyl-[2,2']bipyridinyl | 188893-78-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4,4'-Dimethyl-6,6'-bis-piperidin-1-ylmethyl-[2,2']bipyridinyl
• 英文别名: 4,4'-Dimethyl-6,6'-bis[(piperidin-1-yl)methyl]-2,2'-bipyridine；4-methyl-2-[4-methyl-6-(piperidin-1-ylmethyl)pyridin-2-yl]-6-(piperidin-1-ylmethyl)pyridine
• CAS: 188893-78-9
• 化学式: C₂₄H₃₄N₄
• 分子量: 378.561
• InChiKey: QVEFPXUQWOGPLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  32.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  哌啶 、 6,6'-Bis-bromomethyl-4,4'-dimethyl-[2,2']bipyridinyl 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 以69.1%的产率得到4,4'-Dimethyl-6,6'-bis-piperidin-1-ylmethyl-[2,2']bipyridinyl
  参考文献：
  名称：

  Synthesis and Characterization of Some New Bipyridyl-Based Multidentate Ligands and Their CuI Complexes.

  摘要：

  Four new 2,2'-bipyridyl-based ligands: 6,6'-bis(methylthiomorpholine)-2,2'-bipyridine (L(1)), 4,4'-dimethyl-6,6'-bis(methylthiomorpholine)-2,2'-bipyridine (L(2)), 6,6'-bis(methylpiperidine)-2,2'-bipyridine (L(3)) and 4,4'-dimethyl-6,6'-bis (methylpiperidine)-2,2'-bipyridine (L(4)), and dimeric Cu-I complexes of the ligands L(1) and L(2) have been synthetized. The X-ray crystal structures of the ligands L(1) and L(2) and the L(1)-Cu-I complex have been determined. Complexation of these ligands with other metals produced mainly compounds having very low solubilities.

  DOI：

  10.3891/acta.chem.scand.51-0462