4-hydroxyphenyl(4-nitrobenzyl)methylsulfonium chloride | 133152-71-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-hydroxyphenyl(4-nitrobenzyl)methylsulfonium chloride
• 英文别名: (4-Hydroxyphenyl)(methyl)[(4-nitrophenyl)methyl]sulfanium chloride；(4-hydroxyphenyl)-methyl-[(4-nitrophenyl)methyl]sulfanium;chloride
• CAS: 133152-71-3
• 化学式: C₁₄H₁₄NO₃S*Cl
• 分子量: 311.789
• InChiKey: WABYAYKHKKTHMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.11
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  67
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Li[Al(perfluoro-tertbutoxide)4] 、 4-hydroxyphenyl(4-nitrobenzyl)methylsulfonium chloride 以 二氯甲烷 、 水 为溶剂， 反应 3.0h， 以88%的产率得到4-hydroxyphenyl(4-nitrobenzyl)methylsulfonium tetrakis(nonafluorotert-butyloxy)aluminate
  参考文献：
  名称：

  熱酸発生剤及び硬化性組成物

  摘要：

  提供新型热酸发生剂，其中包含含有化学式（1）所示的含氟烷氧基磺酸铵盐的热酸发生剂。〔R1和R2各自独立地代表烷基或芳基；R3代表H、烷基、羟基、羧基、烷氧基、芳基氧基、烷基羰基、芳基羰基、芳烷基羰基、烷氧羰基、芳基氧羰基等；m为0~5的整数；Rf各自独立地表示70%以上为氟取代的烷基的H；〕【选择图】无

  公开号：

  JP2019085358A

文献信息

• ONIUM SALT AND COMPOSITION COMPRISING THE SAME
  申请人：ASAHI KASEI E-MATERIALS CORPORATION

  公开号：US20160229801A1

  公开（公告）日：2016-08-11

  The onium salt of the present invention contains predetermined compound A represented by the general formula (1). The composition of the present invention contains the onium salt of the present invention, and an onium salt containing predetermined compound B represented by the general formula (2). The onium salt and the composition of the present invention exert well-balanced excellent physical properties in terms of cold curing properties, storage stability, thermal shock resistance after curing, and moisture resistance.

  本发明的季铵盐包含由通式（1）表示的预定化合物A。本发明的组合物包含本发明的季铵盐，以及由通式（2）表示的含有预定化合物B的季铵盐。本发明的季铵盐和组合物在冷固化性能、储存稳定性、固化后的耐热冲击性和耐湿性方面表现出良好的平衡优异物理性能。
• CATIONICALLY POLYMERIZABLE ORGANIC MATERIAL COMPOSITION AND STABILIZATION OF SAID COMPOSITION
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：EP0511405A1

  公开（公告）日：1992-11-04

  A cationically polymerizable organic material composition essentially comprising a cationically polymerizable organic material and a cationic polymerization catalyst, which further contains at least one compound selected from the group consisting of onium salts each having a nucleophilic counter anion represented by halide, perchlorate, alkylsulfate or p-toluenesulfonate ion and salts of iron-aromatic compounds represented by formula (I). The composition is cured by radiation and/or heating and has an excellent storage stability and a long pot life at room temperature out of contact with light.

  一种可阳离子聚合的有机材料组合物，主要包括一种可阳离子聚合的有机材料和一种阳离子聚合催化剂，该组合物还含有至少一种选自以下组别的化合物：具有由卤化物、高氯酸盐、烷基硫酸盐或对甲苯磺酸离子代表的亲核阴离子的鎓盐，以及由式（I）代表的芳香族铁化合物的盐。该组合物通过辐射和/或加热固化，在室温不接触光线的条件下具有极佳的贮存稳定性和较长的罐装寿命。
• Onium salt and composition comprising the same
  申请人：ASAHI KASEI E-MATERIALS CORPORATION

  公开号：US10189781B2

  公开（公告）日：2019-01-29

  The onium salt of the present invention contains predetermined compound A represented by the general formula (1). The composition of the present invention contains the onium salt of the present invention, and an onium salt containing predetermined compound B represented by the general formula (2). The onium salt and the composition of the present invention exert well-balanced excellent physical properties in terms of cold curing properties, storage stability, thermal shock resistance after curing, and moisture resistance.

  本发明的鎓盐含有通式（1）代表的预定化合物 A。本发明的组合物包含本发明的鎓盐和含有通式（2）表示的预定化合物 B 的鎓盐。本发明的鎓盐和组合物在冷固化性能、贮存稳定性、固化后的抗热震性和防潮性方面具有均衡的优异物理性能。
• Sulfonium compound and polymerisation initator comprising the sulfonium compound as the main ingredient
  申请人：SANSHIN KAGAKU KOGYO CO., LTD.

  公开号：EP0393893B1

  公开（公告）日：1995-01-11
• US5359017A
  申请人：——

  公开号：US5359017A

  公开（公告）日：1994-10-25