2,2-dimethyl-2-silabut-3-enyldiphenylphosphine | 100643-34-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-dimethyl-2-silabut-3-enyldiphenylphosphine
• 英文别名: {[Ethenyl(dimethyl)silyl]methyl}(diphenyl)phosphane；[ethenyl(dimethyl)silyl]methyl-diphenylphosphane
• CAS: 100643-34-3
• 化学式: C₁₇H₂₁PSi
• 分子量: 284.413
• InChiKey: WXKIXCNSEIEYFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.09
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  copper(ll) bromide 、 2,2-dimethyl-2-silabut-3-enyldiphenylphosphine 以 甲醇 为溶剂， 以45%的产率得到2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide dimer
  参考文献：
  名称：

  Dimeric 2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide: a chelating olefinic-phosphine copper(I) complex

  摘要：

  The reaction between CuBr2 and 2,2-dimethyl-2-silabut-3-enyldiphenylphosphine (L-1) in methanol produced the title complex 1; the single crystal X-ray crystal structure of 1 reveals a centrosymmetric dimeric bromo-bridged species, with the copper(I) atoms bound to both the olefin and phosphorus donor sites on the ligands. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00105-8

文献信息

• Dimeric 2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide: a chelating olefinic-phosphine copper(I) complex
  作者：Elmer C. Alyea、Paul R. Meehan、George Ferguson、Shanmugaperumal Kannan

  DOI：10.1016/s0277-5387(97)00105-8

  日期：1997.1

  The reaction between CuBr2 and 2,2-dimethyl-2-silabut-3-enyldiphenylphosphine (L-1) in methanol produced the title complex 1; the single crystal X-ray crystal structure of 1 reveals a centrosymmetric dimeric bromo-bridged species, with the copper(I) atoms bound to both the olefin and phosphorus donor sites on the ligands. (C) 1997 Elsevier Science Ltd.