2,3-bis(methylsulfanyl)butane;platinum(2+);2,3,5,6-tetrafluorobenzenethiolate | 219983-20-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3-bis(methylsulfanyl)butane;platinum(2+);2,3,5,6-tetrafluorobenzenethiolate
• CAS: 219983-20-7
• 化学式: C₁₈H₁₆F₈PtS₄
• 分子量: 707.656
• InChiKey: IIOQPCIOZABGAG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.78
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  lead (SC6F4-4-H)2 、 以 丙酮 为溶剂， 以91%的产率得到2,3-bis(methylsulfanyl)butane;platinum(2+);2,3,5,6-tetrafluorobenzenethiolate
  参考文献：
  名称：

  Persulfurated complexes of palladium(II) and platinum(II) with fluorinated aryl-thiolates. X-ray structure of [Pt(SC6F5)2(CH3SCH(CH3)CH(CH3)SCH3)]

  摘要：

  The syntheses of the persulfurated [M(SRF)(2)(CH3SCH(CH3)CH(CH3)SCH3)], M = Pd or Pt; R-F = C6F5 or C6F4H-4 compounds allow the separation of two diastereomers and the NMR detection of five conformers (three anti and two syn) of each compound. H-1, F-19 and Pt-195 NMR data have been used to assign each conformer and to obtain their relative populations as well as to follow their equilibrium at high temperatures. The X-ray diffraction molecular and crystalline structure of [Pt(SC6F5)(2)(CH3SCH(CH3)CH(CH3)SCH3)] has been determined. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00214-9