copper;N-ethyl-N-phenylcarbamodithioate | 53020-87-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper;N-ethyl-N-phenylcarbamodithioate
• CAS: 53020-87-4
• 化学式: C₁₈H₂₀CuN₂S₄
• 分子量: 456.18
• InChiKey: HOGZQCHCQNNPNS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.69
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N-乙基苯胺 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 反应 4.0h， 生成 copper;N-ethyl-N-phenylcarbamodithioate
  参考文献：
  名称：

  某些过渡金属二硫代氨基甲酸酯的合成，表征，热学，抗微生物和抗氧化剂研究

  摘要：

  使用钠N合成了Co（II）[1]，Cu（II）[2]，Mn（II）[3]，Cr（III）[4]和Pd（II）[5]的金属二硫代氨基甲酸酯配合物-乙基-N-苯基二硫代氨基甲酸酯（NaL）。通过元素分析，FTIR和紫外可见光谱技术，磁矩，摩尔电导和热分析（TGA和DSC）对复合物进行表征。红外光谱表明二硫代氨基甲酸酯以对称的双齿形式通过两个硫原子配位。这些配合物的热行为表明，水合配合物在第一步中损失了水分子，随后在最后步骤中使配体分子分解。在这些最终分解步骤中的质量损失考虑表明络合物转化为硫化物。针对某些选定的细菌菌株（大肠杆菌，铜绿假单胞菌，伤寒沙门氏菌和大肠杆菌）评估了复合物的抗菌潜力。金黄色葡萄球菌）和真菌生物（黄曲霉和氧化枯萎病菌）。这些化合物具有广谱的杀菌和杀菌活性，在100μg/ mL的浓度下，其活性超过了对照药物。使用DPPH分析法对配体及其Cu（II）配合物的抗氧化性能进行了体

  DOI：

  10.1007/s11164-016-2709-2

文献信息

• Electron spin resonance study of some copper(II) dithiocarbamates and their mixed-ligand complexes
  作者：William J. Newton、Brian J. Tabner

  DOI：10.1039/dt9810000466

  日期：——

  r. spectra of seven copper(II) dithiocarbamates have been recorded in chloroform–ethanol mixtures at room temperature and at 113 K. It has been found that the addition of a range of salts to these dithiocarbamates destroys the complex forming a mixed-ligand complex, [Cu(S2CNR2)X], with a new e.s.r. spectrum. When X is Cl or Br the additional interaction of the unpaired electron with a single halogen

  在室温和113 K下，在氯仿-乙醇混合物中记录了七种二硫代氨基甲酸铜的esr光谱。已发现向这些二硫代氨基甲酸酯中添加一定范围的盐会破坏该配合物，形成混合配体配合物，[Cu（S 2 CNR 2）X]，具有新的esr光谱。当X为Cl或Br时，观察到未配对电子与单个卤素原子核的其他相互作用。[Cu（S 2 CNEt 2）Cl]络合物形成偶极-偶极耦合二聚体，并且获得了该二聚体的ΔM s = 2吸收率的计算机模拟。
• Method for decomposition of Michael type adduct
  申请人：——

  公开号：US20030204106A1

  公开（公告）日：2003-10-30

  A method for the decomposition of a Michael type adduct of an acrylic acid and/or an acrylic ester represented by the following formula [I] or [II] is disclosed, wherein decomposing the Michael type adduct in the presence of at least one copper salt and at least one metal salt selected from the group consisting of an alkali metal salt and an alkaline earth metal salt into an acrylic acid and/or an acrylic ester and/or an alcohol. CH 2 ═CHCOO(—X—COO) n —R 1 [I] R 2 —O(—X—COO) m —R 3 [II] (wherein n and m denote an integer in the range of 1-5, R 1 , R 2 , and R 3 independently denote a hydrogen atom or an alkyl group, and —X— denotes —CH 2 CH 2 — or —CH(CH 3 )—, and —X— may be identical or different when n is 2 or more).

  本发明公开了一种分解丙烯酸和/或丙烯酸酯的Michael型加合物的方法，所述加合物由以下公式[I]或[II]表示，其中在至少一种铜盐和至少一种金属盐的存在下分解Michael型加合物成为丙烯酸和/或丙烯酸酯和/或醇。CH2═CHCOO(—X—COO)n—R1[I]R2—O(—X—COO)m—R3[II]（其中n和m表示1-5范围内的整数，R1、R2和R3独立地表示氢原子或烷基，—X—表示—CH2CH2—或—CH(CH3)—，当n为2或更多时，—X—可以相同或不同）。
• METHOD OF INHIBITING VINYL COMPOUND POLYMERIZATION
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP0781755A1

  公开（公告）日：1997-07-02

  There is disclosed a process for preventing the polymerization of a vinyl compound which comprises allowing water in an amount of 0.05 to 5% by weight based on the vinyl compound or a corrosion inhibitive substance selected from an alcohol, an inorganic acid or its salt, an aromatic carboxylic acid or its salt and a zinc-containing salt in an amount of preferably 0.01 to 5% by weight based on the same, to coexist with a metallic salt of dithiocarbamic acid, in preventing the polymerization of the vinyl compound with the metallic salt of dithiocarbamic acid. The above process makes it possible to effectively inhibit the polymerization of acrylic acid, methacrylic acid, etc. in the distillation system, etc. of the production process for the above acids as well as the corrosion of the equipment and machinery to be used therein and also to assure long-term stable continuous operation of the equipment and machinery.

  本发明公开了一种防止乙烯基化合物聚合的工艺，该工艺包括允许按乙烯基化合物重量计 0.05%至 5%的量的水或选自醇、无机酸或其盐、芳香族羧酸或其盐以及按重量计优选 0.01%至 5%的量的含锌盐中的缓蚀物质与二硫代氨基甲酸的金属盐共存，以防止乙烯基化合物与二硫代氨基甲酸的金属盐聚合。通过上述工艺，可以有效抑制丙烯酸、甲基丙烯酸等在上述酸类生产工艺的蒸馏系统等中的聚合，以及对其中使用的设备和机械的腐蚀，并确保设备和机械的长期稳定连续运行。
• METHOD FOR INHIBITING POLYMERIZATION OF VINYL COMPOUNDS
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP0855376A1

  公开（公告）日：1998-07-29

  A process for inhibiting polymerization of a vinyl compound comprising using (A) one or both of N-nitrosophenylhydroxylamine and a salt thereof in combination with (B) a salt of copper or in combination with (B') a metal salt of a dialkyldithiocarbamic acid and (C) at least one selected from the group consisting of inorganic acids, salts of inorganic acids, and water. In accordance with the above process, stable continuous operation of a process for producing a vinyl compound, particularly acrylic acid or methacrylic acid, such as a distillation process of the vinyl compound, for a long time is enabled by effectively suppressing polymerization of the vinyl compound in the process or by effectively suppressing polymerization of the vinyl compound in the process while corrosion of the apparatus for the production is prevented.

  一种抑制乙烯基化合物聚合的工艺，包括使用(A)N-亚硝基苯基羟胺及其盐中的一种或两种与(B)铜盐或与(B')二烷基二硫代氨基甲酸的金属盐以及(C)至少一种选自无机酸、无机酸的盐和水组成的组。 根据上述工艺，通过有效抑制乙烯基化合物在生产过程中的聚合，或通过有效抑制乙烯基化合物在生产过程中的聚合，同时防止生产装置的腐蚀，可使生产乙烯基化合物，特别是丙烯酸或甲基丙烯酸的工艺（如乙烯基化合物的蒸馏工艺）长期稳定地连续运行。
• Transparent resin compositions with near infrared absorption characteristics
  申请人：Sumitomo Dow Limited

  公开号：EP0927741A1

  公开（公告）日：1999-07-07

  This invention provides transparent resin compositions of polycarbonate, polyester, methacrylic, styrene, polyvinyl chloride, polyolefin, and polyamide resin, having the advantageous effects of efficiently absorbing near infrared radiation (780-1800 nm) and efficiently transmitting visible light (380-780 nm). The invention provides transparent resin compositions with excellent near infrared absorption characteristics comprising 100 parts by weight of a transparent thermoplastic resin, about 0.01 to about 2 parts by weight of a specific thiuram compound and/or a specific metal dithiocarbamate compound, and about 0.01 to about 2 parts by weight of a specific copper compound. It also provides transparent resin compositions with excellent near infrared absorption characteristics comprising 100 parts by weight of a transparent thermoplastic resin, about 0.01 to about 2 parts by weight of a specific copper dithiocarbamate compound, and about 0 to about 2 parts by weight of a specific copper compound.

  本发明提供了聚碳酸酯、聚酯、甲基丙烯酸、苯乙烯、聚氯乙烯、聚烯烃和聚酰胺树脂的透明树脂组合物，具有高效吸收近红外辐射（780-1800 纳米）和高效透射可见光（380-780 纳米）的优点。 本发明提供了具有优异近红外吸收特性的透明树脂组合物，其中包括按重量计 100 份的透明热塑性树脂、按重量计约 0.01 至约 2 份的特定秋兰姆化合物和/或特定金属二硫代氨基甲酸酯化合物，以及按重量计约 0.01 至约 2 份的特定铜化合物。 本发明还提供了具有优异近红外吸收特性的透明树脂组合物，该组合物包括 100 份（按重量计）透明热塑性树脂、约 0.01 至约 2 份（按重量计）特定二硫代氨基甲酸铜化合物和约 0 至约 2 份（按重量计）特定铜化合物。