carbazol-9-ide;manganese(2+);oxolane | 192750-26-8

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: carbazol-9-ide;manganese(2+);oxolane
• CAS: 192750-26-8
• 化学式: C₃₆H₄₀MnN₂O₃
• 分子量: 603.663
• InChiKey: RFSIMSKJDNOQJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.29
• 重原子数：
  42
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  29.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  carbazol-9-ide;manganese(2+);oxolane 、 咔唑 在 n-BuLi 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Nucleophilic substitution vs. acid–base reactions of [Mn{N(SiMe3)2}2]·2thf; syntheses and structures of 2[Li(thf )4]+[Mn(C12H 8N)4]2−·C6 H5Me and [Mn(C12H8N)2]·3thf (thf = tetrahydrofuran, C12H8N = carbazol-9-yl)

  摘要：

  The ion-separated complex 2[Li(thf) 4 ] + [Mn(C 12 H 8 N) 4 ] 2- 1 has been obtained from the nucleophilic substitution reaction of [Mn{N(SiMe 3 ) 2 } 2 ]·2thf with Li[C 12 H 8 N] (1∶4 equivalents) (thf = tetrahydrofuran, C 12 H 8 N = carbazol-9-yl), and the molecular species [Mn(C 12 H 8 N) 2 ]·3thf 2 from the acid–base reaction of [Mn{N(SiMe 3 ) 2 } 2 ]·2thf and C 12 H 8 NH (1∶2 equivalents). They are among the few amidomanganese(II) complexes containing simple (sterically undemanding) dialkyl- or diaryl-amido groups to be characterised. The crystal structures of both were determined: 1 contains the first tetraamidomanganese(II) dianion and 2 possesses the highest co-ordination number for Mn II in such a compound.

  DOI：

  10.1039/a700765e
• 作为产物：
  描述：

  、 咔唑 在 n-BuLi 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 生成 carbazol-9-ide;manganese(2+);oxolane
  参考文献：
  名称：

  Nucleophilic substitution vs. acid–base reactions of [Mn{N(SiMe3)2}2]·2thf; syntheses and structures of 2[Li(thf )4]+[Mn(C12H 8N)4]2−·C6 H5Me and [Mn(C12H8N)2]·3thf (thf = tetrahydrofuran, C12H8N = carbazol-9-yl)

  摘要：

  The ion-separated complex 2[Li(thf) 4 ] + [Mn(C 12 H 8 N) 4 ] 2- 1 has been obtained from the nucleophilic substitution reaction of [Mn{N(SiMe 3 ) 2 } 2 ]·2thf with Li[C 12 H 8 N] (1∶4 equivalents) (thf = tetrahydrofuran, C 12 H 8 N = carbazol-9-yl), and the molecular species [Mn(C 12 H 8 N) 2 ]·3thf 2 from the acid–base reaction of [Mn{N(SiMe 3 ) 2 } 2 ]·2thf and C 12 H 8 NH (1∶2 equivalents). They are among the few amidomanganese(II) complexes containing simple (sterically undemanding) dialkyl- or diaryl-amido groups to be characterised. The crystal structures of both were determined: 1 contains the first tetraamidomanganese(II) dianion and 2 possesses the highest co-ordination number for Mn II in such a compound.

  DOI：

  10.1039/a700765e