3-氯环戊烯 | 58623-66-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 3-氯环戊烯
• 英文名称: 3-chlorocyclopentene
• 英文别名: 4-Chlor-cyclopenten；4-Chlorcyclopenten；4-Chlorocyclopentene
• CAS: 58623-66-8
• 化学式: C₅H₇Cl
• 分子量: 102.564
• InChiKey: OPIYNVKEBTXQEP-UHFFFAOYSA-N

物化性质

• 沸点：
  122.8±9.0 °C(Predicted)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三甲基氯硅烷 、 3-氯环戊烯 以 四氢呋喃 为溶剂， 生成 Trimethylsilylcyclopenten-3
  参考文献：
  名称：

  Ponec,R. et al., Collection of Czechoslovak Chemical Communications, 1974, vol. 39, p. 1177 - 1184

  摘要：

  DOI：

文献信息

• Substrate specificity in the biosynthesis of cyclopentanoid cyanohydrin glucosides
  作者：Elin S. Olafsdottir、Lise Bolt Jørgensen、Jerzy W. Jaroszewski

  DOI：10.1016/0031-9422(92)80427-g

  日期：1992.12

  were isolated and purified, and the incorporation of the radioactive labels was determined after enzymatic degradation of the glucosides to cyanide. The labels from the amino acid precursors were incorporated into the nitrile group of their corresponding cyanohydrin glucosides, and the incorporation was in each case strongly inhibited by simultaneous feeding with either of the two nitriles. Turnera angustifolia

  摘要 使用完整的植物组织研究了小叶 Turnera 中 deidaclin 和 Passiflora morifolia 中亚麻苦苷的生物合成。放射性标记的前体，2-(2'-环戊烯基)[2- 14 C] 甘氨酸和 l -[U- 14 C]-缬氨酸单独或与假定的腈中间体、2-环戊烯腈和 2 -甲基丙腈。氰醇糖苷被分离和纯化，并在糖苷酶促降解为氰化物后测定放射性标记的掺入。来自氨基酸前体的标记被掺入到它们相应的氰醇糖苷的腈基中，并且在每种情况下通过同时加入两种腈中的任何一种来强烈抑制掺入。
• Polymers containing cyclic ether units joined through 2,6-diyl linkages
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0029725B1

  公开（公告）日：1985-05-02
• COMPOSITIONS AND RELATED METHODS FOR AGRICULTURE
  申请人：Flagship Pioneering Innovations V, Inc.

  公开号：US20210289794A1

  公开（公告）日：2021-09-23

  The invention comprises methods for decreasing colonization by a bacterium of a gut of a stink bug, the method comprising providing a composition comprising vanillin or an analog thereof; and delivering said composition to an egg from which the stink bug will hatch, whereby colonization by the bacterium within the gut of the stink bug hatched from the egg treated with the composition is decreased relative to a stink bug hatched from an untreated egg. In some embodiments, the decrease in colonization by the bacterium decreases the fitness of the stink bug, e.g., decreases reproductive ability, survival, rate of development, number of eggs, number of hatched eggs, adult emergence rate, body length, body width, body mass, or cuticle thickness. In some embodiments of the methods herein, the bacterial colonization-disrupting agent is an inhibitor of bacterial metabolism. In some embodiments, the bacterial colonization-disrupting agent is a polyhydroxyalkanoate (PHA) synthesis inhibitor.
• US4260702A
  申请人：——

  公开号：US4260702A

  公开（公告）日：1981-04-07