[Ag((CH3)2CCHCO2)(triphenylphosphine)2] | 873852-99-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ag((CH3)2CCHCO2)(triphenylphosphine)2]
• CAS: 873852-99-4
• 化学式: C₄₁H₃₇AgO₂P₂
• 分子量: 731.559
• InChiKey: XEQAJYKWGLYHMY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-Butenoic acid, 3-methyl-, silver(1+) salt 、 三苯基膦 以 氯仿 为溶剂， 以95%的产率得到[Ag((CH3)2CCHCO2)(triphenylphosphine)2]
  参考文献：
  名称：

  Synthesis and characterization of triphenylphosphine stabilized silver α,β-unsaturated carboxylate: Crystal structure of [Ag(O2CCHC(CH3)2)(PPh3)2]

  摘要：

  A series of triphenylphosphine coordinated silver alpha,beta-unsaturated carboxylates of type [Ag(O2CR)(PPh3)(n): n = 1, R = CH3CH=CH (2a), (CH3)(2)C=CH (2b), CH3CH2CH=CH (2c), CH3CH2CH2CH=CH (2d), PhCH=CH (2e), CH2=CH (2f); n = 2, CH3CH=CH (3a), (CH3)(2)C=CH (3b), CH3CH2CH=CH (3c), CH3CH2CH2CH=CH (3d)] were prepared by reaction of relative silver carboxylates (1a-1f) with triphenylphosphine in chloroform. These complexes were obtained in high yields and characterized by elemental analysis, H-1 NMR, C-13 NMR, P-31 NMR and IR spectroscopy. Thermal stability of the complexes has been determined by TG analysis. The molecular structure of [Ag((O2CCH=C(CH3)(2)))(PPh3)(2)] (3b) shows that the senecioato ligand is chelated with silver atom and generate, a distorted tetrahedron. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.002