iron compound with niobium (1:1) dihydrate | 117605-08-0

• 分子结构分类: 有机化合物
• 英文名称: iron compound with niobium (1:1) dihydrate
• CAS: 117605-08-0
• 化学式: Fe₀Nb₀O₂
• 分子量: 106.376
• InChiKey: PIKYZQBGLOMSRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.65
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  iron compound with niobium (1:1) dihydrate 在 氧气 作用下， 以 gas 为溶剂， 生成 iron compound with niobium (1:1) trihydrate
  参考文献：
  名称：

  气相中的异核过渡金属簇离子：铁铌的热化学和反应性（NbFe +和NbFeL +； L = O，CO，H2O和烯烃）

  摘要：

  DOI：

  10.1021/j100346a059
• 作为产物：
  描述：

  在 氧气 作用下， 以 gas 为溶剂， 生成 iron compound with niobium (1:1) dihydrate
  参考文献：
  名称：

  气相中的异核过渡金属簇离子：铁铌的热化学和反应性（NbFe +和NbFeL +； L = O，CO，H2O和烯烃）

  摘要：

  DOI：

  10.1021/j100346a059

文献信息

• Structural and electrical conductivity studies on rutile solid solutions [FexTi1-2xMxO2 (M=Nb, Ta)]
  作者：P. ESCRIBANO、F. FABREGAT、G. GARCIA-BELMONTE、E. CORDONCILLO、J. BISQUERT、P. ESCRIBANO

  DOI：10.1023/a:1004434009509

  日期：1998.8

  In this study, FexTi1-xMxO2 (M = Nb, Ta; 0 less than or equal to x less than or equal to 0.5) solid solutions have been synthesized from both ceramic and gel methods, and electrical and structural characterization has been carried out. The solid solutions show rutile structure except for the case of FeNbO4, which forms an orthorhombic structure. The electrical behaviour of the system studied corresponds to extrinsic p-type semiconduction and it is related to the presence of Fe(II) ions. Conductivity is enhanced by local distortions of the MO lengths associated with ordering oxidation states such as those in Fe3O4. The distortions are more frequent when the asymmetry is greater (M = Nb). No electrical changes have been detected when the synthesis method is different. (C) 1998 Kluwer Academic Publishers.
• Preparation and magnetic properties of Fe3+–Nb5+ co-doped SnO2
  作者：Yu Wang、Guangsheng Pang、Yan Chen、Shihui Jiao、Dong Wang、Shouhua Feng

  DOI：10.1016/j.jssc.2007.11.019

  日期：2008.2

  Fe3+-Nb5+ co-doped SnO2 was prepared at 1200 degrees C by a simple chemical co-precipitation method. The Sn1-2xFexNbxO2 solid solutions kept cassiterite structure in the range of 0 < x <= 0.33, and their cell parameters decrease with increasing x. While x = 0.40, a second phase with orthorhombic FeNbO4 structure co-exists with the cassiterite phase, and the second phase becomes dominant while x >= 0.45. The magnetic measurements indicated that low doping ratio sample (x=0.03) exhibits paramagnetic behavior. A paramagnetic-to-antiferromagnetic phase transition was observed for the samples with higher doping ratio (x >= 0.15). (c) 2007 Elsevier Inc. All rights reserved.