N-o-hydroxybenzimido-meso-tetraphenylporphyrinatozinc(II) | 1206463-05-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: N-o-hydroxybenzimido-meso-tetraphenylporphyrinatozinc(II)
• CAS: 1206463-05-9
• 化学式: C₅₁H₃₃N₅O₂Zn
• 分子量: 813.245
• InChiKey: FYVRLAOUUTUYEL-YJBLFHCDSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-o-hydroxy benzamido-meso-tetraphenylporphyrin 、 zinc(II) acetate dihydrate 以 甲醇 、 二氯甲烷 为溶剂， 以78%的产率得到N-o-hydroxybenzimido-meso-tetraphenylporphyrinatozinc(II)
  参考文献：
  名称：

  Metal complexes of tetradentate and pentadentate N-o-hydroxybenzamido-meso-tetraphenylporphyrin ligand: M(N-NCO(o-OH)C6H4-tpp) (M=Zn2+, Ni2+, Cu2+) and M′(N-NCO(o-O) C6H4-tpp) (M′=Mn3+) (tpp=5, 10, 15, 20-tetraphenylporphyrinate)

  摘要：

  The crystal structures of N-o-hydroxybenzimido-meso-tetraphenylporphyrinatozinc(II) toluene solvate [Zn(N-NCO(o-OH)C6H4-tpp)center dot C6H5CH3; 4 center dot C6H5CH3], N-o-hydroxybenzimido-meso-tetraphenylporphyrinatonickel(II) chloroform solvate [Ni(N-NCO(o-OH)C6H4-tpp)center dot 0.6CHCl(3); 5 center dot 0.6 CHCl3], N-o-hydroxybenzimido-meso-tetraphenylporphyrinatocopper(II) toluene solvate [Cu(N-NCO(o-OH)C6H4-tpp)center dot C6H5CH3; 6.C6H5CH3] and N-o-oxido-benzimido-meso-tetraphenylporphyrinato(-kappa(4),N-1,N-2,N-3,N-5,kappa O-2) manganese (III) methylene chloride. methanol solvate [Mn(N-NCO(o-O)C6H4-tpp)center dot CH2Cl2 center dot MeOH; 8 center dot CH2Cl2 center dot MeOH] were established. The coordination sphere around Zn2+ ion in 4 center dot C6H5CH3, (or Ni2+ ion in 5-0.6 CHCl3 or Cu2+ ion in 6 center dot C6H5CH3) is a distorted square planar (DSP) whereas for Mn3+ in 8 center dot CH2Cl2 center dot MeOH, it is a distorted trigonal bipyramid (DTBP) with O(1). N(1) and N(3) lying in the equatorial plane for 8 center dot CH2Cl2 center dot MeOH. The g value of 8.27 measured from the parallel polarization of X-band EPR spectra at 293 K is consistent with the high-spin mononuclear manganese(III) (S = 2) in 8. The magnitude of axial (D) zero-field splitting (ZFS) for the mononuclear Mn(III) in 8 was determined approximately as 3.0 cm(-1) by the paramagnetic susceptibility measurements and conventional EPR spectroscopy. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.09.009