2,5-dibromo-3-[4'-(aminomethyl)phenyl]thiophene | 1234783-62-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,5-dibromo-3-[4'-(aminomethyl)phenyl]thiophene
• 英文别名: [4-(2,5-Dibromothiophen-3-yl)phenyl]methanamine
• CAS: 1234783-62-0
• 化学式: C₁₁H₉Br₂NS
• 分子量: 347.073
• InChiKey: QWPRRDWCNVVUTP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  54.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,5-dibromo-3-[4'-(aminomethyl)phenyl]thiophene 、 N-(1-octylnonyl)perylene-3,4:9,10-tetracarboxylic-3,4-anhydride-9,10-imide 在 咪唑 、 zinc diacetate 作用下， 反应 2.0h， 以84%的产率得到C₅₂H₅₀Br₂N₂O₄S
  参考文献：
  名称：

  Synthesis of Conjugated Fluorene-alt-thiophene Polymers with Pendant Perylenediimide Units

  摘要：

  In this article we present the synthesis, characterization, electrochemical, optical, and preliminary photophysical investigation of two novel poly(fluorene-alt-thiophene) conjugated polymers endowed with pendant perylenediimide electron acceptor units. We show a route to the synthesis of easily functionalizable monomers paving the way to the preparation of a variety of functionalized polymers with different properties and applications and reflecting the versatility of this synthetic methodology.

  DOI：

  10.1021/jo100816j
• 作为产物：
  描述：

  N-[[4-(2,5-dibromothiophen-3-yl)phenyl]methylidene]hydroxylamine 在 lithium aluminium tetrahydride 作用下， 以 甲苯 为溶剂， 反应 26.0h， 以86%的产率得到2,5-dibromo-3-[4'-(aminomethyl)phenyl]thiophene
  参考文献：
  名称：

  Synthesis of Conjugated Fluorene-alt-thiophene Polymers with Pendant Perylenediimide Units

  摘要：

  In this article we present the synthesis, characterization, electrochemical, optical, and preliminary photophysical investigation of two novel poly(fluorene-alt-thiophene) conjugated polymers endowed with pendant perylenediimide electron acceptor units. We show a route to the synthesis of easily functionalizable monomers paving the way to the preparation of a variety of functionalized polymers with different properties and applications and reflecting the versatility of this synthetic methodology.

  DOI：

  10.1021/jo100816j

文献信息

• Synthesis of Conjugated Fluorene-<i>alt</i>-thiophene Polymers with Pendant Perylenediimide Units
  作者：Rafael Gómez、Carlos Seoane、José L. Segura

  DOI：10.1021/jo100816j

  日期：2010.8.6

  In this article we present the synthesis, characterization, electrochemical, optical, and preliminary photophysical investigation of two novel poly(fluorene-alt-thiophene) conjugated polymers endowed with pendant perylenediimide electron acceptor units. We show a route to the synthesis of easily functionalizable monomers paving the way to the preparation of a variety of functionalized polymers with different properties and applications and reflecting the versatility of this synthetic methodology.