[Co(HPO3)(pyridine)] | 1030599-14-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Co(HPO3)(pyridine)]
• 英文别名: [Co(HPO3)(py)]
• CAS: 1030599-14-4
• 化学式: C₅H₅N*Co*HO₃P
• 分子量: 218.075
• InChiKey: AXBXBDFJTIIGPP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.82
• 重原子数：
  11.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.08
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  [Co(HPO3)(pyridine)] 以 neat (no solvent) 为溶剂， 生成 cobalt(II) pyrophosphate
  参考文献：
  名称：

  Syntheses, structures and magnetic properties of two new one-dimensional cobalt (II) phosphites with organic amines acting as ligands

  摘要：

  Two new one-dimensional (ID) inorganic-organic hybrid cobalt (II) phosphites Co(HPO3) (py) (1) and [Co(OH)(py)(3)][Co(py)(2)] [HPO2(OH)](3) (2) have been prepared under solvothermal conditions in the presence of pyridine (py). Compound I crystallizes in the monoclinic system, space group p2(1)/c, a = 5.3577(7)angstrom, b = 7.7503(10) angstrom, c = 17.816(2) angstrom, beta= 94.327(2)degrees, V = 737.67(16) angstrom(3), Z = 4. Compound 2 is orthorhombic, Cmcm, a = 16.3252(18) angstrom, b = 15.7005(16) angstrom, c = 13.0440(13) angstrom = 90.00 degrees V = 3343.4(6)angstrom(3) and Z = 4. Compound I possesses a ID ladder-like framework constructed from CoO3N tetrahedral, HPO3 pseudo-pyramids and pyridine ligands. While compound 2 is an unusual inorganic organic hybrid ID chain, which consists of corner-shared six-membered rings made of CoO3N3/CoO4N2 octahedra and HPO3 pseudo-pyramids through sharing vertices. (c) 2008 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2008.01.043
• 作为产物：
  描述：

  吡啶 、 亚磷酸 、 cobalt(II) chloride hexahydrate 在 HF 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 [Co(HPO3)(pyridine)]
  参考文献：
  名称：

  Syntheses, structures and magnetic properties of two new one-dimensional cobalt (II) phosphites with organic amines acting as ligands

  摘要：

  Two new one-dimensional (ID) inorganic-organic hybrid cobalt (II) phosphites Co(HPO3) (py) (1) and [Co(OH)(py)(3)][Co(py)(2)] [HPO2(OH)](3) (2) have been prepared under solvothermal conditions in the presence of pyridine (py). Compound I crystallizes in the monoclinic system, space group p2(1)/c, a = 5.3577(7)angstrom, b = 7.7503(10) angstrom, c = 17.816(2) angstrom, beta= 94.327(2)degrees, V = 737.67(16) angstrom(3), Z = 4. Compound 2 is orthorhombic, Cmcm, a = 16.3252(18) angstrom, b = 15.7005(16) angstrom, c = 13.0440(13) angstrom = 90.00 degrees V = 3343.4(6)angstrom(3) and Z = 4. Compound I possesses a ID ladder-like framework constructed from CoO3N tetrahedral, HPO3 pseudo-pyramids and pyridine ligands. While compound 2 is an unusual inorganic organic hybrid ID chain, which consists of corner-shared six-membered rings made of CoO3N3/CoO4N2 octahedra and HPO3 pseudo-pyramids through sharing vertices. (c) 2008 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2008.01.043