[Zn(1,3-adamantanediacetate)(2,4'-dipyridylamine)] | 1224853-17-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Zn(1,3-adamantanediacetate)(2,4'-dipyridylamine)]
• CAS: 1224853-17-1
• 化学式: C₁₀H₉N₃*C₁₄H₁₈O₄*Zn
• 分子量: 486.886
• InChiKey: YXRHXRWCCQKOQI-XRFJUSQSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.07
• 重原子数：
  32.0
• 可旋转键数：
  6.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  118.07
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  2,4'-dipyridylamine 、 1,3-金刚烷二乙酸 、 zinc(II) acetate dihydrate 在 KOH 作用下， 以 甲醇 、 水 为溶剂， 以53%的产率得到[Zn(1,3-adamantanediacetate)(2,4'-dipyridylamine)]
  参考文献：
  名称：

  Two novel d10 frameworks based on a new V-shaped ligand 2,4′-dipyridylamine and a flexible dicarboxylate ligand

  摘要：

  Via hydrothermal synthesis, the self-assembly of d(10) metal, 2,4'-dipyridylamine (L) and 1,3-adamantanediacetic acid (H(2)ADA) generated two unprecedented coordination polymers [Zn(ADA)(L)](n) (1) and [Cd(ADA)(L)(2)]. (2). Complex I possesses a novel I D looped-chain topology structure decorated with arms. Complex 2 shows an extended threaded framework involving 2D coordination layers of square (4(4)) topology with dangling ligands, which gives the novel (2D -> 3D) polythreaded array. To the best of our knowledge, complex 2 is the first example with four dangling arms coordinated in the axial sites of dinuclear nodes. In addition, both of the complexes show strong photoluminescence at room temperature, and may be good candidates for potential luminescence materials. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.08.009