| 159125-27-6

• CAS: 159125-27-6
• 化学式: C₁₂H₁₇MnO₅Te
• 分子量: 423.802
• InChiKey: SGIRIDLJXVPDTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  pentacarbonyl(methyl)manganese(I) 、 二异丙基碲 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  The formation and thermal decomposition of some alkyl- and acetyl-manganesecarbonyl complexes with dialkyltellurium ligands

  摘要：

  Treatment of MeMn(CO)(5) with the dialkyltellurium compounds TeR(2) (R = Me, Et, Pr-i) gave the acyl complexes MeCOMn(CO)(4)(TeR(2)) in high yield. A similar reaction between EtCOMn(CO)(5) and TeR(2) (R = Me, Et) yielded the related complexes EtCOMn(CO)(4)(TeR(2)). When the benzyl complex BzMn(CO)(5) was treated with TeR(2) (R = Me, Et), BzCOMn(CO)(4)(TeR(2)) was formed initially but, on prolonged reaction in a refluxing solvent, decarbonylation occurred to form BzMn(CO)(4)(TeR(2)). Related bromo complexes BrMn(CO)(4)(TeR(2)) were obtained when BrMn(CO)(5) was treated with TeR(2) (R = Me, Et). Spectroscopic results indicated that all of the TeR(2) substitution products have octahedral stereochemistry about manganese with a cis-configuration of the tellurium ligand and the organo or halo group. Some of the complexes were selected for assessment as possible MOCVD single source precursors. Although most of the compounds are liquids with significant volatility, they tend to dissociate when heated with release of the dialkyl-tellurium. Nonetheless, pyrolysis of the compounds R'COMn(CO)(4)(TeR(2)) (with R' = Me and R = Me, Et or Pr-i; R' = Et and R = Et) under typical MOCVD conditions (H-2 stream, 175-225 degrees C) produced metal films containing manganese and tellurium

  DOI：

  10.1016/s0277-5387(00)88140-1