N-(1,1'-biphenyl-4-yl)-N-[4-(dibenzothiophen-4-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine | 1356174-57-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(1,1'-biphenyl-4-yl)-N-[4-(dibenzothiophen-4-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine
• 英文别名: N-(4-dibenzothiophen-4-ylphenyl)-9,9-dimethyl-N-(4-phenylphenyl)fluoren-2-amine
• CAS: 1356174-57-6
• 化学式: C₄₅H₃₃NS
• 分子量: 619.83
• InChiKey: YGJSZDLENCSIPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  47
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  对溴碘苯 在 四(三苯基膦)钯 、 三叔丁基膦 、 potassium carbonate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 水 、 甲苯 为溶剂， 反应 16.0h， 生成 N-(1,1'-biphenyl-4-yl)-N-[4-(dibenzothiophen-4-yl)phenyl]-9,9-dimethyl-9H-fluoren-2-amine
  参考文献：
  名称：

  유기 광전자 소자 및 표시 장치

  摘要：

  两极相对，正极和负极之间，包括含有以化学式1表示的化合物的发光层，以及位于正极和发光层之间，包括含有以化学式2表示的化合物的载流子传输层的有机光电子器件和包括该有机光电子器件的显示器件。【化学式1】 【化学式2】 在化学式1中，X，Ar，Ar，R至R，L至L，Ar至Ar如规范中所定义。

  公开号：

  KR20160012846A

文献信息

• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE À BASE DE CES COMPOSÉS
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2012015265A1

  公开（公告）日：2012-02-02

  Provided are novel organic electroluminescent compounds and an organic electroluminescent device using the same. Because the organic electroluminescent device using the organic electroluminescent compound as a hole transport material or a hole injection material exhibits good luminous efficiency and excellent lifetime properties, it is used to manufacture OLED devices having superior operating lifetime and consuming less power due to improved power efficiency.

  提供了新型有机电致发光化合物和使用该化合物的有机电致发光装置。由于使用该有机电致发光化合物作为空穴传输材料或空穴注入材料的有机电致发光装置表现出良好的发光效率和优秀的寿命特性，因此用于制造具有卓越工作寿命且由于提高的功率效率而消耗更少电力的OLED设备。
• [EN] ORGANIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, DISPLAY DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] COMPOSÉ ORGANIQUE, ÉLÉMENT LUMINESCENT, DISPOSITIF LUMINESCENT, DISPOSITIF D'AFFICHAGE, DISPOSITIF ÉLECTRONIQUE, ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2014157018A1

  公开（公告）日：2014-10-02

  A novel organic compound represented by a formula (G1) that forms an exciplex emitting light with high efficiency is provided. By the use of the organic compound and an organic compound with an electron-transport property, an exciplex that emits light with extremely high efficiency can be formed.[In the formula (G1), A, R1, R2 are as defined in the claims.]

  提供一种由(G1)式表示的新型有机化合物，该化合物形成一个发光效率高的激复合物。通过使用该有机化合物和具有电子传输特性的有机化合物，可以形成发光效率极高的激复合物。[在(G1)式中，A，R1，R2如权利要求所定义。]
• ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE INCLUDING SAME
  申请人：Cheil Industries Inc.

  公开号：EP2940097A1

  公开（公告）日：2015-11-04

  An organic optoelectronic device and a display device including the same are disclosed, and the organic optoelectronic device includes an anode, a cathode and at least one organic layer interposed between the anode and the cathode, wherein the organic thin layer includes an emission layer, a hole transport layer, a hole injection layer, an electron transport layer, an electron injection layer, or a combination thereof, the organic thin layer includes an emission layer and a plurality of a hole transport layer, the hole transport layer contacting the emission layer of the plurality of hole transport layer includes a compound represented by a combination of the following Chemical Formula 1; Chemical Formula 2 or 3; and Chemical Formula 4, and one of the hole transport layers not contacting the emission layer includes a compound represented by the following Chemical Formula B-1.

  本发明公开了一种有机光电器件和包括该器件的显示器件，该有机光电器件包括阳极、阴极和至少一个穿插在阳极和阴极之间的有机薄层，其中有机薄层包括发射层、空穴传输层、空穴注入层、电子传输层、电子注入层或其组合，有机薄层包括发射层和多个空穴传输层，空穴传输层与多个空穴传输层中的发射层接触、电子传输层、电子注入层或它们的组合，有机薄层包括发射层和多个空穴传输层，与发射层接触的多个空穴传输层包括由以下化学式 1；化学式 2 或 3 和化学式 4 的组合，而不与发射层接触的孔传输层之一包括由以下化学式 B-1 表示的化合物。
• Organic compound, light-emitting element, light-emitting device, display device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10446766B2

  公开（公告）日：2019-10-15

  A novel organic compound that forms an exciplex emitting light with high efficiency is provided. An organic compound with a triarylamine skeleton in which the three aryl groups of the triarylamine skeleton are a p-biphenyl group, a fluoren-2-yl group, and a phenyl group to which a dibenzofuranyl group or a dibenzothiophenyl group is bonded. By the use of the organic compound and an organic compound with an electron-transport property, an exciplex that emits light with extremely high efficiency can be formed.

  本发明提供了一种新型有机化合物，它能形成一种高效发光的复合物。一种有机化合物具有三芳基胺骨架，其中三芳基胺骨架的三个芳基分别是对联苯基、芴-2-基和与二苯并呋喃基或二苯并噻吩基键合的苯基。通过使用该有机化合物和具有电子传输特性的有机化合物，可以形成一种发光效率极高的复合物。
• ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE INCLUDING THE SAME
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20150280136A1

  公开（公告）日：2015-10-01

  An organic optoelectronic device and a display device including the same are disclosed, and the organic optoelectronic device includes an anode, a cathode and at least one organic layer interposed between the anode and the cathode, wherein the organic thin layer includes an emission layer, a hole transport layer, a hole injection layer, an electron transport layer, an electron injection layer, or a combination thereof, the organic thin layer includes an emission layer and a plurality of a hole transport layers, the hole transport layer contacting the emission layer of the plurality of hole transport layer includes a compound represented by a combination of Chemical Formula 1, Chemical Formula 2 or 3, and Chemical Formula 4, and one of the hole transport layers not contacting the emission layer includes a compound represented by Chemical Formula B-1.