1,8,15,22-tetraamino zinc phthalocyanine | 160988-56-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 1,8,15,22-tetraamino zinc phthalocyanine
• 英文别名: Zinc(II) 1,8,15,22-tetra(amino)phthalocyanine；zinc;2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene-5,14,23,32-tetramine
• CAS: 160988-56-7
• 化学式: C₃₂H₂₀N₁₂Zn
• 分子量: 637.981
• InChiKey: WTQFPIPEBYBVGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.45
• 重原子数：
  45
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  180
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,8,15,22-tetraamino zinc phthalocyanine 在 吡啶 、 吡啶盐酸盐 作用下， 反应 17.0h， 以77%的产率得到1,8,15,22-Tetra-aminophthalocyanine
  参考文献：
  名称：

  [EN] PREPARATION AND USES OF GUANIDINIUM-MODIFIED PORPHYRINS AND PHTHALOCYANINES
  [FR] PRÉPARATION ET UTILISATIONS DE PORPHYRINES ET PHTALOCYANINES MODIFIÉES PAR LA GUANIDINE

  摘要：

  公开号：

  WO2010028780A3
• 作为产物：
  描述：

  1,8,15,22-tetranitrophthalocyanatozinc (II) 在 sodium sulfide 作用下， 反应 5.0h， 生成 1,8,15,22-tetraamino zinc phthalocyanine
  参考文献：
  名称：

  Novel catalyst of zinc tetraamino-phthalocyanine supported by multi-walled carbon nanotubes with enhanced visible-light photocatalytic activity

  摘要：

  采用化学嫁接方法成功制备了由多壁碳纳米管（MWCNTs）支持的四氨基酞菁锌（ZnTAPc）杂化材料，并报道了它们的光催化行为。

  DOI：

  10.1039/c5ra10462a

文献信息

• Synthesis, structural investigations and biological studies on symmetrically substituted 3,3′,3",3"′-tetra-methoxyphenylimino phthalocyanine complexes
  作者：M. H. Moinuddin khan、Fasiulla、J. Keshavayya、K. R. Venugopala Reddy

  DOI：10.1134/s0036023608010117

  日期：2008.1

  The present paper describes the synthesis and characterization of novel metal (II) 3,3',3aEuro(3),3aEuro '-tetramethoxyphenylimino substituted phthalocyanines (M-MeOPhImPcs) of copper (II), cobalt (II), nickel (II) and zinc (II) by condensing the 3,3',3aEuro(3),3aEuro(3)aEuro(2)-tetra amino phthalocyanines with anisaldehyde. The dark bluish green colored tetraimino substituted phthalocyanine derivatives were characterized by various physico-chemical techniques like elemental analysis, magnetic susceptibility, electronic, IR, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of inter molecular co-operative interactions. The complexes were also evaluated for their antifungal and antibacterial activities.
• Synthesis, spectral and magnetic susceptibility studies on tetrachloro metal(II)phthalocyanines
  作者：M.P. Somashekarappa、K.R. Venugopala Reddy、M.N.K. Harish、J. Keshavayya

  DOI：10.1016/j.molstruc.2005.05.012

  日期：2005.10

  The present paper describes a simple method for the synthesis of symmetrically substituted 1,8,15,22-tetrachloro phthalocyanines of copper, cobalt, nickel and zinc. The title complexes are synthesized from the corresponding tetraamino metal phthalocyanines by modified Sandmeyers method and in turn the tetraamino metal phthalocyanines are prepared from 3-nitrophthalic acid. The bluish-green coloured tetrachloro metal phthalocyanine complexes are characterized by elemental, electronic, IR, magnetic susceptibility and X-ray powder diffraction studies to check the purity and the structural integrity. The magnetic susceptibility studies revealed that, the experimental values are higher than that of the spin only value magnetic moment, and the presence of intermolecular co-operative effects. (c) 2005 Elsevier B.V. All rights reserved.