(maleonitriledithilato)(1,4-bis(diphenylphosphino)butane)nickel(II) | 81098-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (maleonitriledithilato)(1,4-bis(diphenylphosphino)butane)nickel(II)
• 英文别名: Ni(dppb)(mnt)
• CAS: 81098-03-5
• 化学式: C₃₂H₂₈N₂NiP₂S₂
• 分子量: 625.357
• InChiKey: AKSIMJZZXMDIKU-LWFKIUJUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.37
• 重原子数：
  39.0
• 可旋转键数：
  4.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  47.58
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 Na{1,2-dicyanoethylene-1,2-dithiolate}*H2O 、 1,4-双(二苯基膦)丁烷 以 丙酮 为溶剂， 以98%的产率得到(maleonitriledithilato)(1,4-bis(diphenylphosphino)butane)nickel(II)
  参考文献：
  名称：

  Planar Ni(II) 1,2-dithiolenes involving bidentate P-donor ligands

  摘要：

  A series of planar Ni(II) dithiolenes derived of maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt) and toluene-3,4-dithiol (tdt) with bidentate P,P-ligands (dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino)propane, dppb = 1,4-bis(diphenylphosphino)butane, dpppn = 1,5-bis(diphenylphosphino)pentane) of the [Ni(P,P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, conductivity measurements and thermal analysis. Single crystal X-ray analysis of [Ni(dpppn)(mnt)] confirmed a planar geometry of NiP2S2 chromophore. Possible practical applications such as use of these compounds for vulcanization accelerators and their anticholinesterase activity were evaluated. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.067

文献信息

• Spectroelectrochemistry of nickel complexes. Voltammetric and ESR studies of the redox reactions of phosphine-dithiolate and phosphine-catecholate complexes of nickel
  作者：G. A. Bowmaker、P. D. W. Boyd、G. K. Campbell

  DOI：10.1021/ic00136a056

  日期：1982.6