N,N',N''-(2,2':6',2''-terpyridine)(4-nitrobenzenethiolato)platinum(II) chloride | 96729-00-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N',N''-(2,2':6',2''-terpyridine)(4-nitrobenzenethiolato)platinum(II) chloride
• 英文别名: 2,6-dipyridin-2-ylpyridine;4-nitrobenzenethiolate;platinum(2+);chloride
• CAS: 96729-00-9
• 化学式: C₂₁H₁₅N₄O₂PtS*Cl
• 分子量: 617.975
• InChiKey: MGEOPLNUIFSRCF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.71
• 重原子数：
  30
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  85.5
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  tetrafluoroboric acid 、 N,N',N''-(2,2':6',2''-terpyridine)(4-nitrobenzenethiolato)platinum(II) chloride 以 乙醇 、 水 为溶剂， 生成 N,N',N''-(2,2':6',2''-terpyridine)(4-nitrobenzenethiolato)platinum(II) tetrafluoroborate
  参考文献：
  名称：

  摘要：

  Three mixed-ligand terpyridine-thiolate Pt-II complexes containing 2,2':6',2"-terpyridine (tpy) and para-substituted thiophenolate ions, [(tpy)Pt(SC6H4-4-X)]BF4 (X = NMe2, H, NO2) were synthesized. The complexes were isolated as chlorides or tetrafluoroborates and characterized by electrochemistry, visible electronic spectroscopy and H-1 NMR spectroscopy, and elemental analysis. Remarkable influence of the electron-donating/withdrawing properties of the substituent in the thiolate ligand on the physicochemical properties of the complexes, in particular, on the electrochemical reduction potentials, was found. The reduced forms of the complexes undergo electrochemically initiated alkylation with alkyl halides, resulting in the formation of Pt alkyl compounds.

  DOI：

  10.1023/a:1024909325619
• 作为产物：
  描述：

  chloro(2,2':6',2''-terpyridine)platinum(II) chloride dihydrate 、 4-硝基苯硫醇 在 potassium tert-butylate 作用下， 以 乙醇 、 水 为溶剂， 生成 N,N',N''-(2,2':6',2''-terpyridine)(4-nitrobenzenethiolato)platinum(II) chloride
  参考文献：
  名称：

  摘要：

  Three mixed-ligand terpyridine-thiolate Pt-II complexes containing 2,2':6',2"-terpyridine (tpy) and para-substituted thiophenolate ions, [(tpy)Pt(SC6H4-4-X)]BF4 (X = NMe2, H, NO2) were synthesized. The complexes were isolated as chlorides or tetrafluoroborates and characterized by electrochemistry, visible electronic spectroscopy and H-1 NMR spectroscopy, and elemental analysis. Remarkable influence of the electron-donating/withdrawing properties of the substituent in the thiolate ligand on the physicochemical properties of the complexes, in particular, on the electrochemical reduction potentials, was found. The reduced forms of the complexes undergo electrochemically initiated alkylation with alkyl halides, resulting in the formation of Pt alkyl compounds.

  DOI：

  10.1023/a:1024909325619