| 1622885-27-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1622885-27-1
• 化学式: C₂₆H₃₀Br₄CuN₄O₄
• 分子量: 845.711
• InChiKey: RONFPBFHUIXVPP-BSGNKXHSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 2,4-dibromo-6-[(2-morpholin-4-ylethylimino)methyl]phenol 以 甲醇 为溶剂， 反应 1.0h， 以62%的产率得到
  参考文献：
  名称：

  TWO NEW SCHIFF BASE NI II AND CU II COMPLEXES: SYNTHESIS AND STRUCTURES

  摘要：

  Schiff base ligands 2-bromo-4-chloro-6-[(2-piperidin-1-ylethylimino) methyl] phenol (BCP) and 2,4-dibromo-6-[(2-morpholin-4-ylethylimino) methyl] phenol (DBP) and their nickel(II) and copper(II) complexes [Ni(BCP)(2)(CH3OH)(2)]center dot 2NO(3) (1) and [Cu(DBP)(2)] (2), have been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination. The crystal of (1) is orthorhombic: space group Pbcn, a = 23.894(1), b = 8.244(2), c = 19.900(2) angstrom, V = 3919.9(10) angstrom(3), Z = 4. The crystal of (2) is monoclinic: space group P2(1)/c, a = 7.072(2), b = 15.426(3), c = 14.214(3) angstrom, beta = 96.718(2)degrees, V = 1540.0(7) angstrom(3), Z = 2. The Schiff bases coordinate to the metal atoms through the phenolate O and imine N atoms. The Ni atom in (1) is in an octahedral coordination, and the Cu atom in (2) is in a square planar coordination.

  DOI：

  10.4067/s0717-97072013000300019