| 226999-11-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• CAS: 226999-11-7
• 化学式: C₂₇H₂₉NO₂P₂PdS₂Se
• 分子量: 710.992
• InChiKey: FPGKKGVAMYHVJS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.15
• 重原子数：
  36.0
• 可旋转键数：
  10.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  31.35
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  chloro(diethyl dithiophosphato-S,S')(triphenylphosphine-P)palladium(II) 、 sodium 2-pyridyl selenolate 以 甲醇 、 二氯甲烷 为溶剂， 以84%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of monomeric palladium(II) pyridine-2-chalcogenolate complexes

  摘要：

  Mononuclear palladium(II) complexes of the type [Pd(Epy)((SS)-S-boolean AND)(PPh3)] [E = S or Se; (SS)-S-boolean AND = S2CNEt2, S2P(OR)(2) (R = Et, Pr-n, Pr-i)] have been prepared. All the complexes have been characterized by elemental analysis and NMR (H-1, P-31{H-1}, Se-77{H-1}) spectral data. The NMR data indicate that there are two species in solution, i.e. one with chelating (SS)-S-boolean AND ligand predominates (similar to 95%) while the other with chelating Epy and monodentate (SS)-S-boolean AND existing in similar to 5% concentration. The X-ray crystal structure of [Pd(Spy){S2P(OPri)(2)}(PPh3)] has been determined. The square planar palladium atom is coordinated to asymmetrically chelated ((PrO)-O-i)(2)PS2- ligand, PPh3 and pyS(-) groups. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00426-4