邻三联苯-D14 | 5142-67-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 邻三联苯-D14
• 英文名称: o-terphenyl-d14
• 英文别名: perdeuterated orthoterphenyl；tetradecadeuterio-o-terphenyl；1,2,3,4,5-pentadeuterio-6-[2,3,4,5-tetradeuterio-6-(2,3,4,5,6-pentadeuteriophenyl)phenyl]benzene
• CAS: 5142-67-6
• 化学式: C₁₈H₁₄
• 分子量: 244.198
• InChiKey: OIAQMFOKAXHPNH-WZAAGXFHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  邻三联苯 在 氘代苯 、 二氯乙基铝 作用下， 生成 邻三联苯-D14
  参考文献：
  名称：

  ²H‐NMR study of the glass transition in supercooled ortho‐terphenyl

  摘要：

  The glass forming molecular liquid ortho-terphenyl has been investigated by 2H-NMR techniques providing spin-relaxation times (T1, T2), and spin-alignment data which yield information on the time scale and geometry of ultra-slow molecular reorientation. The main results are as follows: The primary glass transition (α process) is characterized by rotational molecular jumps with a jump size distribution weighted in favor of large jump angles, and by a distribution of correlation times. In addition intramolecular flip–flop jumps of the lateral phenyl rings are found which do not take part in the α process. Apart from this (secondary) intramolecular dynamics no residual small angle reorientation persists below Tg on the time scale (10−4 to 102 s) of the spin-alignment experiment.

  DOI：

  10.1063/1.454047