1-methoxy-4-(5-oxo-2-tert-butyl-3,4-diaza-1-oxa-cyclopent-2-en-4-yl)-benzene | 1739-73-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-methoxy-4-(5-oxo-2-tert-butyl-3,4-diaza-1-oxa-cyclopent-2-en-4-yl)-benzene
• 英文别名: 5-tert-butyl-3-(4-methoxyphenyl)-1,3,4-oxadiazol-2-one
• CAS: 1739-73-7
• 化学式: C₁₃H₁₆N₂O₃
• 分子量: 248.282
• InChiKey: LPTDGCOIFRBTML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  51.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-methoxy-4-(5-oxo-2-tert-butyl-3,4-diaza-1-oxa-cyclopent-2-en-4-yl)-benzene 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 生成 1-hydroxy-4-(5-oxo-2-tert-butyl-3,4-diaza-1-oxa-cyclopent-2-en-4-yl)-benzene
  参考文献：
  名称：

  [EN] PESTICIDAL HETEROCYCLIC DIHALOALLYL COMPOUNDS
  [FR] DERIVES D'ALLYLE HETEROCYCLIQUE

  摘要：

  公开号：

  WO2005068445A3
• 作为产物：
  描述：

  光气 、 N'-(4-methoxyphenyl)pivalohydrazide 以 DMF (N,N-dimethyl-formamide) 、 甲苯 为溶剂， 反应 7.0h， 生成 1-methoxy-4-(5-oxo-2-tert-butyl-3,4-diaza-1-oxa-cyclopent-2-en-4-yl)-benzene
  参考文献：
  名称：

  [EN] PESTICIDAL HETEROCYCLIC DIHALOALLYL COMPOUNDS
  [FR] DERIVES D'ALLYLE HETEROCYCLIQUE

  摘要：

  公开号：

  WO2005068445A3

文献信息

• Pesticidal Heterocyclic Dihaloallyl Compounds
  申请人：Hall Graham Roger

  公开号：US20070299064A1

  公开（公告）日：2007-12-27

  The invention relates to compounds of formula wherein Het, A 1 , A 2 , A 3 , A 4 , D, W, T, Q, Y, X 1 , X 2 , R 1 , R 2 , R 3 , R 4 , k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.

  本发明涉及化合物的公式，其中Het、A1、A2、A3、A4、D、W、T、Q、Y、X1、X2、R1、R2、R3、R4、k和m如上所定义，以及在适用的情况下，可能的E/Z异构体、E/Z异构体混合物和/或它们的互变异构体，每种情况下均为自由形式或盐形式，制备这些化合物、E/Z异构体、E/Z异构体混合物和/或互变异构体的方法，以及使用这些化合物、E/Z异构体、E/Z异构体混合物和/或互变异构体的农药组合物，其中活性成分已从这些化合物、E/Z异构体、E/Z异构体混合物和/或互变异构体中选择，每种情况下均为自由形式或农业化学可用盐形式，制备这些组合物的方法以及使用这些组合物处理的植物繁殖材料，控制害虫的方法，中间体以及在适用的情况下，可能的E/Z异构体、E/Z异构体混合物和/或互变异构体，每种情况下均为自由形式或盐形式，用于制备这些化合物、E/Z异构体、E/Z异构体混合物和/或互变异构体的制备方法以及使用这些中间体和，可能的E/Z异构体、E/Z异构体混合物和/或互变异构体。
• PESTICIDAL HETEROCYCLIC DIHALOALLYL COMPOUNDS
  申请人：Hall Roger Graham

  公开号：US20100197696A1

  公开（公告）日：2010-08-05

  The invention relates to compounds of formula wherein Het, A 1 , A 2 , A 3 , A 4 , D, W, T, Q, Y, X 1 , X 2 , R 1 , R 2 , R 3 , R 4 , k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.

  本发明涉及以下式的化合物， 其中，Het，A1，A2，A3，A4，D，W，T，Q，Y，X1，X2，R1，R2，R3，R4，k和m如上所定义，并且，在适当的情况下，可能的E/Z异构体，E/Z异构体的混合物和/或其互变异构体，每种情况均为自由形式或盐形式，涉及制备这些化合物，E/Z异构体，E/Z异构体的混合物和/或其互变异构体的方法，以及使用这些化合物，E/Z异构体，E/Z异构体的混合物和/或其互变异构体制备杀虫剂组合物，在其中活性成分已从这些化合物，E/Z异构体，E/Z异构体的混合物和/或其互变异构体中选择，每种情况均为自由形式或农用盐形式，涉及制备和使用这些组合物的方法，以及使用这些组合物处理的植物繁殖材料，控制害虫的方法，中间体，以及在适当的情况下，可能的E/Z异构体，E/Z异构体的混合物和/或其互变异构体，每种情况均为自由形式或盐形式，用于制备这些化合物，E/Z异构体，E/Z异构体的混合物和/或其互变异构体的制备方法，以及使用这些中间体和，在适当的情况下，可能的E/Z异构体，E/Z异构体的混合物和/或其互变异构体。
• Pesticidal heterocyclic dihaloallyl compounds
  申请人：Syngenta Crop Protection, Inc.

  公开号：US07723362B2

  公开（公告）日：2010-05-25

  The invention relates to compounds of formula wherein Het, A1, A2, A3, A4, D, W, T, Q, Y, X1, X2, R1, R2, R3, R4, k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.

  本发明涉及以下式子的化合物： 其中，Het，A1，A2，A3，A4，D，W，T，Q，Y，X1，X2，R1，R2，R3，R4，k和m的定义如上所述，以及在适用的情况下，可能的E/Z异构体，E/Z异构体混合物和/或其互变异构体，均以自由形式或盐形式存在，涉及到制备这些化合物，E/Z异构体，E/Z异构体混合物和/或其互变异构体的方法，以及这些化合物，E/Z异构体，E/Z异构体混合物和/或其互变异构体的农药组合物的使用，其中活性成分已从这些化合物，E/Z异构体，E/Z异构体混合物和/或其互变异构体中选择，均以自由形式或农用可用盐形式存在，涉及到制备和使用这些组合物的方法，以及用这些组合物处理的植物繁殖材料，控制害虫的方法，中间体，以及在适用的情况下，可能的E/Z异构体，E/Z异构体混合物和/或其互变异构体，均以自由形式或盐形式存在，用于制备这些化合物，E/Z异构体，E/Z异构体混合物和/或其互变异构体的方法，以及制备和使用这些中间体和可能的E/Z异构体，E/Z异构体混合物和/或其互变异构体的方法。
• US7723362B2
  申请人：——

  公开号：US7723362B2

  公开（公告）日：2010-05-25
• [EN] HETEROCYCLIC ALLYL DERIVATIVES<br/>[FR] DERIVES D'ALLYLE HETEROCYCLIQUE
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2005068445A2

  公开（公告）日：2005-07-28

  The invention relates to compounds of formula (I) wherein Het, A1, A2, A3, A4, D, W, T, Q, Y, X1, X2, R1, R2, R3, R4, k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.