| 417706-69-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 417706-69-5
• 化学式: C₁₀H₂₇N₄P*C₂₄H₂₀B*H
• 分子量: 554.567
• InChiKey: TZXOGAZIFRUDGZ-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  5.59
• 重原子数：
  40.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  22.08
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  以 乙腈 为溶剂， 生成 叔丁基亚氨基-三(二甲氨基)正膦
  参考文献：
  名称：

  Bicyclic Guanidinium Tetraphenylborate: A Photobase Generator and A Photocatalyst for Living Anionic Ring-Opening Polymerization and Cross-Linking of Polymeric Materials Containing Ester and Hydroxy Groups

  摘要：

  1,5,7-Triazabicyclo[4,4,0]dec-5-ene (TBD) with pK(a) of 26.03 in acetonitrile can be effectively released by photolysis of TBD center dot HBPh4 salt, which represents a new family of short-wave UV photobase generators. This photobase generator enables the photoinduced living ring-opening polymerization of cyclic esters and the photoinduced cross-linking of various polymeric materials containing the hydroxyl-ester groups.

  DOI：

  10.1021/ja802816g
• 作为产物：
  描述：

  四苯硼钠 、 叔丁基亚氨基-三(二甲氨基)正膦 在 盐酸 作用下， 以 水 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Bicyclic Guanidinium Tetraphenylborate: A Photobase Generator and A Photocatalyst for Living Anionic Ring-Opening Polymerization and Cross-Linking of Polymeric Materials Containing Ester and Hydroxy Groups

  摘要：

  1,5,7-Triazabicyclo[4,4,0]dec-5-ene (TBD) with pK(a) of 26.03 in acetonitrile can be effectively released by photolysis of TBD center dot HBPh4 salt, which represents a new family of short-wave UV photobase generators. This photobase generator enables the photoinduced living ring-opening polymerization of cyclic esters and the photoinduced cross-linking of various polymeric materials containing the hydroxyl-ester groups.

  DOI：

  10.1021/ja802816g