Pd(1,4-bis(diisopropylphosphino)butane)2 | 148508-74-1

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: Pd(1,4-bis(diisopropylphosphino)butane)2
• 英文别名: 4-Di(propan-2-yl)phosphanylbutyl-di(propan-2-yl)phosphane;palladium
• CAS: 148508-74-1
• 化学式: C₃₂H₇₂P₄Pd
• 分子量: 687.239
• InChiKey: CCPBZIMRPLFTAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.73
• 重原子数：
  37
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Pd(1,4-bis(diisopropylphosphino)butane)2 、 氯苯 以 not given 为溶剂， 生成 trans-Pd(1,4-bis(diisopropylphosphino)butane)2 (Ph)Cl 、 cis-Pd(1,4-bis(diisopropylphosphino)butane)(Ph)Cl
  参考文献：
  名称：

  Palladium-catalyzed vinylation of aryl chlorides. Chelate effect in catalysis

  摘要：

  By use of the dippb ligand (dippb = 1,4-bis-(diisopropylphosphino)butane) it is possible to effect the synthetically useful Pd-catalyzed direct vinylation of aryl chlorides; the reaction tolerates various substituents and generally results in high yields. The reaction is very sensitive to the nature of the chelating ligand, probably as a result of the need for chelate opening to allow olefin coordination and chelate closure to promote insertion. Monophosphines are ineffective. A mechanistic scheme is presented.

  DOI：

  10.1021/om00042a008