mer-hydrido-(1-carbonyl-2-oxo-5-phenylcyclohexenediyl)tris(trimethylphosphane)cobalt(III) | 210900-83-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: mer-hydrido-(1-carbonyl-2-oxo-5-phenylcyclohexenediyl)tris(trimethylphosphane)cobalt(III)
• 英文别名: mer-PhC6H7O2Co(H)(PMe3)3；mer-hydrido-(1-carbonyl-2-oxo-5-phenyl-cyclohexenediyl)tris(trimethylphosphine)cobalt(III)
• CAS: 210900-83-7
• 化学式: C₂₂H₄₀CoO₂P₃
• 分子量: 488.473
• InChiKey: YENCSJIYIJDKHO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  mer-hydrido-(1-carbonyl-2-oxo-5-phenylcyclohexenediyl)tris(trimethylphosphane)cobalt(III) 、 1，4-二苯基丁二炔 以 正戊烷 为溶剂， 以41%的产率得到(1-carbonyl-2-oxo-5-phenyl-cyclohexenediyl)-[(Z)-1-phenylethinyl-2-phenylethenyl]-trans-bis(trimethylphosphine)cobalt(III)
  参考文献：
  名称：

  Novel stable five-coordinate diorgano cobalt(III) complexes: Formation, structure, and reaction with carbon monoxide

  摘要：

  A series of new five-coordinate acyl vinyl cobalt(III) complexes Co{eta(1)-C(C CPh)=CHPh}[C(O)-C=C-O]L-2(L=PMe3) (6-10) were prepared via formal insertion of diphenylbutadiyne into Co-H function of mer-octahedral hydrido-acyl(phenolato)-cobalt(III) complexes. The complexes are diamagnetic. One square pyramidal structure of complex 6 was confirmed by X-ray diffraction analysis. These complexes are stable in solid state. In solution, six-coordinate acyl vinyl carbonyl cobalt(III) complex 11 is approved through the reaction of complex 7 with CO and the structure of complex 11 was determined by X-ray method. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.03.029
• 作为产物：
  描述：

  methyltetrakis(trimethylphosphine)cobalt(I) 、 2-hydroxy-5-phenylcyclohex-1-enecarbaldehyde 以 正戊烷 为溶剂， 以70%的产率得到mer-hydrido-(1-carbonyl-2-oxo-5-phenylcyclohexenediyl)tris(trimethylphosphane)cobalt(III)
  参考文献：
  名称：

  Klein, Hans-Friedrich; Haller, Stefan; Sun, Hongjian, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1998, vol. 53, # 5-6, p. 587 - 598

  摘要：

  DOI：

文献信息

• Reactivity of mer-hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(iii) complex
  作者：Qingfen Niu、Hongjian Sun、Lin Wang、Qingping Hu、Xiaoyan Li

  DOI：10.1039/c3dt52519h

  日期：——

  The reactivity of mer-hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III) complex 1 was intensively studied. A series of sulfur-coordinated organocobalt complexes (2–8) were obtained through the reactions of 1 with RX (RX = HCl, C2H5Br and CH3I), 2-(diphenylphosphanyl)phenol, 2-(diphenylphosphino)benzenethiol, and CO. The reaction of complex 1 with ethynyltrimethylsilane under 1 bar of CO

  的反应性聚体-hydrido（2- mercaptobenzoyl）三（三甲基膦）钴（III）配合物1被进行了深入研究。通过1与RX（RX = HCl，C 2 H 5 Br和CH 3 I），2-（二苯基膦基）苯酚，2-（二苯基膦基）的反应获得了一系列硫配位的有机钴配合物（2-8）。配合物1与乙炔基三甲基硅烷在1 bar的CO下反应，通过C的插入反应得到五配位钴（I）配合物11乙炔基三甲基硅烷的C键成Co–H键，然后进行C，C偶联反应（还原消除）。提出了11的形成机理，并进行了部分实验验证。作为中间体的四坐标钴（我）络合物13通过复杂的反应，分离1与无CO的乙炔基。配合物的晶体结构2-4，8和11是由X射线衍射测定。
• Reaction of the Acyl(hydrido)cobalt(III) Complex with 2-Propyn-1-ol
  作者：Lei She、Hongjian Sun、Xiaoyan Li

  DOI：10.1002/zaac.200700206

  日期：2007.10

  Acyl(hydrido)cobalt(III) complexes mer-[CoIII(O∩C=O)(H)(PMe3)3] (1 and 2) stabilized by 2-acylphenolato-chelating ligands and with the support of trimethylphosphine react with 2-propyn-1-ol to generate inserting products of alkyne bond into Co-H bond bearing bis-chelating vinyl cobalt(III) complexes cis-[CoIII(O∩C=O)(HO∩C=CH2)(PMe3)2] (3 and 4). In complexes 3 and 4 the vinyl chelating ligands form

  酰基（氢化）钴（III）配合物 mer-[CoIII(O∩C=O)(H)(PMe3)3]（1 和 2）由 2-酰基苯酚螯合配体稳定并在三甲基膦的支持下与 2 -propyn-1-ol 生成炔键插入产物到 Co-H 键中，带有双螯合乙烯基钴 (III) 配合物 cis-[CoIII(O∩C=O)(HO∩C=CH2)(PMe3)2 ]（3 和 4）。在配合物 3 和 4 中，乙烯基螯合配体形成一个新的四元螯合环。通过X射线衍射分析配合物3的单晶。
• Klein, Hans-Friedrich; Li, Xiaoyan; Floerke, Ulrich, Zeitschrift fur Naturforschung, B: Chemical Sciences, 2000, vol. 55, # 8, p. 707 - 717
  作者：Klein, Hans-Friedrich、Li, Xiaoyan、Floerke, Ulrich、Haupt, Hans-Juergen

  DOI：——

  日期：——