[Rh(cod)(η2-P,P'-PrN(PPh2)2)]*(OTf)*CDCl3 | 1437793-98-0

• 英文名称: [Rh(cod)(η2-P,P'-PrN(PPh2)2)]*(OTf)*CDCl3
• CAS: 1437793-98-0
• 化学式: CF₃O₃S*CHCl₃*C₃₅H₃₉NP₂Rh
• 分子量: 907.995
• InChiKey: HDKKCABGAZXKRW-HQZNNISNSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氘代氯仿 、 [Rh(cod)(η2-P,P'-PrN(PPh2)2)]*(OTf) 生成 [Rh(cod)(η2-P,P'-PrN(PPh2)2)]*(OTf)*CDCl3
  参考文献：
  名称：

  Highly Active Hydroformylation Catalysts: Synthesis, Characterisation and Catalytic Performance

  摘要：

  The phoszone ligand [(Ph2P)(bis-3,5-CF3-Ph)]NN=CH(penta-fluoro-Ph) transformed in liquid CO2 at room temperature in presence of [Rh(cod)(2)]OTf into [Rh(cod)(eta(2)-P,P'-Ph2POPPh2)]OTf. Replacing the O-atom in Ph2POPPh2 by a PrN-group leads to the ligand PrN(PPh2)(2) acting similarly as a bidentate ligand in [Rh(cod)(eta(2)-P,P'-PrN(PPh2)(2))]OTf. Hydroformylation of 1-octene with in situ catalysts formed by the ligands with [Rh(cod)(2)]OTf showed hydroformylation activities at 50 % conversion of 16,000 h(-1) (PrN(PPh2)(2)/[Rh(cod)(2)]OTf) and 24,000 h(-1) (phoszone/[Rh(cod)(2)]OTf), respectively.

  DOI：

  10.1007/s10562-013-1010-x