| 1616778-51-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1616778-51-8
• 化学式: C₁₆H₃₁NiOP₃S
• 分子量: 423.099
• InChiKey: VDJYOYMJXAWUTH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 碘甲烷 以 乙腈 为溶剂， 反应 0.5h， 以40%的产率得到
  参考文献：
  名称：

  Synthesis of novel organonickel(II) complexes with thiosalicylaldehyde as a chelate ligand

  摘要：

  Two sulfur-coordinated acyl nickel(II) complexes 3 and 4 Ni(S boolean AND C@O)(PMe3)(3) (boolean AND = phenyl (3), 5-methylphenyl (4)) were synthesized by reactions of thiosalicylaldehyde (1) and 5-methylthiosalicylal-dehyde (2) with NiMe2(PMe3)(3). Complex 3 reacted with excess iodomethane affording (2-methyl-mercapto-phenyl)nickel(II) complex 5. The mechanisms of formation of 3-5 were proposed and discussed. The molecular structures of 4 and 5 were determined by X-ray diffraction. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.05.001
• 作为产物：
  描述：

  [bis(methyl)tris(trimethylphosphane)nickel(II)] 、 2-硫代水杨醛 以 乙醚 为溶剂， 反应 16.0h， 以47.1%的产率得到
  参考文献：
  名称：

  Synthesis of novel organonickel(II) complexes with thiosalicylaldehyde as a chelate ligand

  摘要：

  Two sulfur-coordinated acyl nickel(II) complexes 3 and 4 Ni(S boolean AND C@O)(PMe3)(3) (boolean AND = phenyl (3), 5-methylphenyl (4)) were synthesized by reactions of thiosalicylaldehyde (1) and 5-methylthiosalicylal-dehyde (2) with NiMe2(PMe3)(3). Complex 3 reacted with excess iodomethane affording (2-methyl-mercapto-phenyl)nickel(II) complex 5. The mechanisms of formation of 3-5 were proposed and discussed. The molecular structures of 4 and 5 were determined by X-ray diffraction. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.05.001