diphenyl[4-(phenylthio)phenyl]-sulfonium bromide | 524678-36-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: diphenyl[4-(phenylthio)phenyl]-sulfonium bromide
• 英文别名: dipheny-4-phenylthiophenylsulfonium bromide；diphenyl-(4-phenylsulfanylphenyl)sulfanium;bromide
• CAS: 524678-36-2
• 化学式: Br*C₂₄H₁₉S₂
• 分子量: 451.451
• InChiKey: ABZDICOQQVXTQP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.94
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  diphenyl[4-(phenylthio)phenyl]-sulfonium bromide 、 potassium nonaflate 以 二氯甲烷 、 水 为溶剂， 反应 1.0h， 以26.3 g的产率得到diphenyl[4-(phenylthio)phenyl]-sulfonium nonaflate
  参考文献：
  名称：

  METHOD OF MANUFACTURING SULTONIUM SALT

  摘要：

  提供一种亚砜盐的制备方法，可以减少单亚砜盐的产生。制备亚砜盐的方法包括：准备含有亚砜阳离子和第一阴离子的第一亚砜盐，通过将第一阴离子与卤离子交换来制备第二亚砜盐，通过将卤离子与第二阴离子交换来制备第三亚砜盐。

  公开号：

  US20160068477A1
• 作为产物：
  描述：

  二苯基亚砜 在 氢溴酸 、 焦磷酸 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 4.33h， 生成 diphenyl[4-(phenylthio)phenyl]-sulfonium bromide
  参考文献：
  名称：

  METHOD OF MANUFACTURING SULTONIUM SALT

  摘要：

  提供一种亚砜盐的制备方法，可以减少单亚砜盐的产生。制备亚砜盐的方法包括：准备含有亚砜阳离子和第一阴离子的第一亚砜盐，通过将第一阴离子与卤离子交换来制备第二亚砜盐，通过将卤离子与第二阴离子交换来制备第三亚砜盐。

  公开号：

  US20160068477A1

文献信息

• Hybrid onium salt
  申请人：Ishihara Masami

  公开号：US20050020710A1

  公开（公告）日：2005-01-27

  The present invention relates to a hybrid type onium salt having an iodonium salt and a sulfonium salt in the molecule, useful, for example, as a cationic type photopolymerization initiator and an acid generator for a chemically amplified resist and provides a hybrid type onium salt shown by the general formula [1]: [wherein R 1 to R 3 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which maybe substituted; Q 1 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T 1 is an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; and R 4 is an alkyl group, an alkenyl group, an aryl group or an aralkyl group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted or a group shown by the general formula [2]: (wherein R 5 to R 7 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which maybe substituted; Q 2 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T 2 an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; A 3 is a counter anion; m is an integer of 0 to 4; and two ns are each independently an integer of 0 to 5); A 1 and A 2 are each independently a counter anion; and m and n are the same as described above], and a polymerization initiator or an acid generator, comprising said onium salt.

  本发明涉及一种杂化型离子盐，其分子中具有碘化离子盐和亚砜盐，例如，作为阳离子型光聚合引发剂和化学放大型抗蚀剂的酸发生剂有用，并提供由通式[1]所示的杂化型离子盐：[其中R1至R3分别独立地是卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或氨基，可被取代；Q1是直链、氧原子、硫原子或较低的烷基链；T1是烷基或芳基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基；R4是烷基、烯丙基、芳基或芳基烷基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基或由通式[2]所示的基：（其中R5至R7分别独立地是卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或氨基，可被取代；Q2是直链、氧原子、硫原子或较低的烷基链；T2是烷基或芳基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基；A3是一个对离子；m是0到4的整数；两个n各自独立地是0到5的整数）；A1和A2各自独立地是一个对离子；m和n与上述描述相同]，以及包含该离子盐的聚合引发剂或酸发生剂。
• Hybrid type onium salt
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：US07101918B2

  公开（公告）日：2006-09-05

  The present invention relates to a hybrid type onium salt having an iodonium salt and a sulfonium salt in the molecule, Useful, for example, as a cationic type photopolymerization initiator and an acid generator for a chemically amplified resist and provides a hybrid type onium salt shown by the general formula [1]: and R4 is an alkyl group, an alkenyl group, an aryl group or an aralkyl group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted or a group shown by the general formula [2]: and a polymerization initiator or an acid generator, comprising said onium salt.

  本发明涉及一种混合型离子盐，其分子中含有碘离子盐和磺离子盐，例如可用作阳离子型光聚合引发剂和化学增感抗蚀剂的酸发生剂，并提供了一种由通式[1]所示的混合型离子盐，其中R4是一种烷基、烯基、芳基或芳烷基，可以具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和氨基中选择的取代基或由通式[2]所示的基团。本发明还涉及包含该离子盐的聚合引发剂或酸发生剂。
• HYBRID ONIUM SALT
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：EP1443042B1

  公开（公告）日：2008-08-13
• US7101918B2
  申请人：——

  公开号：US7101918B2

  公开（公告）日：2006-09-05