[(PCy3)Pt(μ-PCy2)]2 | 1025043-95-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环化合物
• 英文名称: [(PCy3)Pt(μ-PCy2)]2
• CAS: 1025043-95-1
• 化学式: C₆₀H₁₁₀P₄Pt₂
• 分子量: 1345.59
• InChiKey: TUWLNKJXTLPTGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22.12
• 重原子数：
  66.0
• 可旋转键数：
  12.0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  cis-dichlorobis(dicyclohexylphosphane)platinum(II) 以 二氯甲烷 、 水 、 丙酮 、 甲苯 为溶剂， 生成 [(PCy3)Pt(μ-PCy2)]2
  参考文献：
  名称：

  Reactivity of a Phosphinito-Bridged Pt^I−Pt^I Complex with Nucleophiles: Substitution versus Addition

  摘要：

  As a result of the strong electrophilic character of the Pt bound to O, the phosphinito-bridged Pt-I complex [(PHCy2)Pt(mu-PCy2){kappa P-2, O-mu-P(O)Cy-2}Pt(PHCy2)](Pt-Pt) (1) undergoes attack at the O-bound Pt atom by molecules such as di- and tricyclohexylphosphane, dicyclohexylphosphane oxide, and dicyclohexylphosphane sulfide. Thus, reaction of 1 with PHCy2 gives the symmetric Pt-I dimer [(PHCy2)Pt(mu-PCy2)](2)(Pt-Pt) (2), while the hydrido-bridged complex syn-[(PHCy2)[kappa P-P(O)Cy-2[Pt(mu-PCy2)(mu-H)Pt(PHCy2){kappa P-P(O)Cy-2}](Pt-Pt) (4) is obtained from reaction of 1 with P(O)HCy2; the thiophosphinito complex [(PHCy2)Pt(mu-PCy2){kappa P-2,S-mu-P(S)Cy-2}Pt(PHCy2)](Pt-Pt) (8) forms selectively in reaction of 1 with P(S)HCy2. For comparison, the reaction with PCy3 results only in ligand substitution, affording [(PCy3)Pt(mu-PCy2){kappa P-2,O-mu-P(O)Cy-2)Pt(PHCy2)](Pt-Pt) (5). DFT studies confirmed the remarkable electrophilicity of the oxygen-bound Pt and shed light on the nature of the metal-metal bond in Pt dimers.

  DOI：

  10.1021/ic800045u