1,3-Bis(pyren-1-ylmethylamino)propan-2-ol | 1299469-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1,3-Bis(pyren-1-ylmethylamino)propan-2-ol
• CAS: 1299469-74-1
• 化学式: C₃₇H₃₀N₂O
• 分子量: 518.658
• InChiKey: IVCUUCQZJZQHQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  40
• 可旋转键数：
  8
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  44.3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 以0.414 g的产率得到1,3-Bis(pyren-1-ylmethylamino)propan-2-ol
  参考文献：
  名称：

  Fluorescence sensing of Cu2+ and Hg2+ by a dipyrene ligand involving an excimer-switch off mechanism

  摘要：

  A novel dipyrene ligand 1 has been designed which shows intramolecular excimer formation in solution. Its specific interaction with Cu2+ or Hg2+ leads to the disruption of the excimer and results in a fluorescence-mediated sensing of these ions in a mixed organic-aqueous solution. Apart from steady-state studies, time-resolved fluorescence measurements also reveal that excimer-switch off caused by metal ion coordination leads to the selective detection of these ions. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.02.051