3-溴苯基硼酸 | 859940-48-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-溴苯基硼酸
• 英文名称: 3-bromophenylboric acid
• 英文别名: (3-bromophenoxy)boronic acid
• CAS: 859940-48-0
• 化学式: C₆H₆BBrO₃
• 分子量: 216.827
• InChiKey: ITZYPLMJTLJHGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-溴吡啶 、 3-溴苯基硼酸 在 sodium carbonate 作用下， 生成 2-(3-溴苯)吡啶
  参考文献：
  名称：

  METAPHENYLENE POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME

  摘要：

  一种聚合物化合物，包括由以下化学式（2）表示的构造单元和由以下化学式（1）表示的构造单元，其中R1代表烷基基团或类似物，R2和R3各自独立地代表氢原子或类似物，-Ar1-（2），其中Ar1代表芳基基团或类似物。在由Ar1表示的基团中，氢原子可以被烷基基团、芳基团或类似物替代。

  公开号：

  US20110272686A1

文献信息

• COMPOSITION COMPRISING NITROGEN-CONTAINING HETEROCYCLIC COMPOUND
  申请人：Anryu Makoto

  公开号：US20110108770A1

  公开（公告）日：2011-05-12

  A composition comprising a compound represented by the following formula (1): wherein Ar represents an aryl group or a mono-valent heterocyclic group.) or a compound having a residue of a compound represented by the above-described formula (1), and a compound represented by the following formula (2): wherein one member of Z 1 to Z 3 represents —N═ and two remainders thereof each represent —C(R′)═; Z 4 and Z 5 each represent —C(R′)═; one member of Z 6 to Z 8 represents —N═ and two remainders thereof each represent —C(R′)═; Z 9 and Z 10 each represent —C(R′)═; R′ represents a substituent such as a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an aryloxy group and the like. or a compound having a residue of a compound represented by the above-described formula (2).

  一种组合物，包括由以下式子（1）所表示的化合物：其中Ar代表芳基或单价杂环基；或者具有上述式子（1）所表示化合物的残基的化合物，以及由以下式子（2）所表示的化合物：其中Z1至Z3中的一个成员表示—N═，其余两个残基分别表示—C(R′)═；Z4和Z5各自表示—C(R′)═；Z6至Z8中的一个成员表示—N═，其余两个残基分别表示—C(R′)═；Z9和Z10各自表示—C(R′)═；R′表示取代基，例如氢原子、烷基、烷氧基、芳基、芳氧基等；或者具有上述式子（2）所表示化合物的残基的化合物。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Soga Masayuki

  公开号：US20120199825A1

  公开（公告）日：2012-08-09

  An organic electroluminescent device comprising an anode, a cathode, a light emitting layer that is disposed between the anode and the cathode and contains a first light emitting layer material containing a phosphorescent compound and a second light emitting layer material containing a charge transporting polymer compound (that is, a light emitting layer containing a first light emitting layer material and a second light emitting layer material), and a hole transporting layer that is disposed between the anode and the light emitting layer so as to be adjacent to the light emitting layer and is composed of a hole transporting polymer compound, wherein the lowest excitation triplet energy T1 e (eV) of the first light emitting layer material, the lowest excitation triplet energy T1 h (eV) of the second light emitting layer material and the lowest excitation triplet energy T1 t (eV) of the hole transporting polymer compound satisfy the following formulae (A) and (B): T 1 e ≦T 1 h (A) T 1 t −T 1 e ≦0.10  (B). An organic electroluminescent device comprising an anode and a cathode, and a hole transporting layer and a light emitting layer disposed between the anode and the cathode, wherein the hole transporting layer contains 1) a mixture of 2,2′-bipyridine and/or 2,2′-bipyridine derivative and a non-2,2′-bipyridinediyl group-containing hole transporting polymer compound, 2) a 2,2′-bipyridinediyl group-containing polymer compound having a constitutional unit composed of an unsubstituted or substituted 2,2′-bipyridinediyl group, and at least one constitutional unit selected from the group consisting of constitutional units composed of a divalent aromatic amine residue and constitutional units composed of an unsubstituted or substituted arylene group, or a combination thereof.

  一种有机电致发光器件，包括阳极、阴极、位于阳极和阴极之间且含有第一发光层材料和第二发光层材料的发光层（即含有第一发光层材料和第二发光层材料的发光层），其中第一发光层材料含有磷光化合物，第二发光层材料含有电荷传输聚合物化合物，以及位于阳极和发光层之间以与发光层相邻的方式设置的孔传输层，由孔传输聚合物化合物组成，其中第一发光层材料的最低激发三重态能量T1e（eV）、第二发光层材料的最低激发三重态能量T1h（eV）和孔传输聚合物化合物的最低激发三重态能量T1t（eV）满足以下公式（A）和（B）：T1e≦T1h（A）T1t−T1e≦0.10（B）。一种有机电致发光器件，包括阳极和阴极、孔传输层和发光层，位于阳极和阴极之间，其中孔传输层包含1）2,2′-联吡啶和/或2,2′-联吡啶衍生物的混合物和不含2,2′-联吡啶基团的孔传输聚合物化合物，2）具有由未取代或取代的2,2′-联吡啶基团组成的构成单元和至少选自由双价芳香胺残基和由未取代或取代的芳基烃基组成的构成单元之一的构成单元的2,2′-联吡啶基团含量聚合物化合物，或其组合。
• CYCLOALKYLAMINE DERIVATIVES
  申请人：Marumoto Shinji

  公开号：US20120295943A9

  公开（公告）日：2012-11-22

  Provided is a therapeutic agent for hyperparathyroidism, renal osteodystrophy, hypercalcemia and the like, which has a CaSR activating (agonist) action. A compound represented by the following general formula (1): [wherein, Ar which is a partial structure in the general formula (1) represents a phenyl group or a naphthyl group; R 1a and R 1b are the same or different from each other, and represent a hydrogen atom, a halogeno group, or the like; R 2a and R 2b are the same or different from each other, and represent a hydrogen atom, a halogeno group, or the like; A represents a single bond, an oxygen atom, or the like; B represents a single bond, a C1-C4 alkanediyl group, or the like; Z represents a carboxyl group or a tetrazolyl group; and m represents an integer of 1 to 3] or a pharmacologically acceptable salt thereof.

  提供了一种治疗甲状旁腺功能亢进、肾性骨营养不良、高钙血症等疾病的治疗剂，具有CaSR激活（激动剂）作用。该化合物由以下通式（1）表示：[其中，通式（1）中的部分结构Ar表示苯基或萘基；R1a和R1b相同或不同，表示氢原子，卤素基团或类似物；R2a和R2b相同或不同，表示氢原子，卤素基团或类似物；A表示单键，氧原子或类似物；B表示单键，C1-C4烷二基基团或类似物；Z表示羧基或四唑基；m表示1至3的整数]或其药学上可接受的盐。
• POLYMERIC COMPOUND HAVING RESIDUE OF NITROGEN-CONTAINING HETEROCYCLIC COMPOUND
  申请人：Anryu Makoto

  公开号：US20110118411A1

  公开（公告）日：2011-05-19

  A polymer compound having a residue of a compound represented by the following formula (1): wherein Ar represents an aryl group or mono-valent heterocyclic group.) and a residue of a compound represented by the following formula (2): wherein one member of Z 1 to Z 3 represents —N═ and two remainders thereof each represent —C(R′)═. Z 4 and Z 5 each represent —C(R′)═. One member of Z 6 to Z 8 represents —N═ and two remainders thereof each represent —C(R′)═. Z 9 and Z 10 each represent —C(R′)═. R′ represents a hydrogen atom, alkyl group or the like).

  具有以下式子（1）所代表的化合物残基（其中Ar代表芳基或一价杂环基）和以下式子（2）所代表的化合物残基的聚合物化合物：其中Z1到Z3中的一个成员表示—N═，其余两个残基各代表—C（R′）═。Z4和Z5分别表示—C（R′）═。Z6到Z8中的一个成员表示—N═，其余两个残基各代表—C（R′）═。Z9和Z10分别表示—C（R′）═。R′表示氢原子、烷基或类似物。
• Metaphenylene polymer compound and light emitting device using the same
  申请人：Ohuchi Kazuei

  公开号：US09112154B2

  公开（公告）日：2015-08-18

  A polymer compound comprising a constitutional unit represented by the following formula (2) and a constitutional unit represented by the following formula (1), wherein R1 represents an alkyl group or the like, and R2 and R3 each independently represent a hydrogen atom or the like, —Ar1—  (2) wherein Ar1 represents an arylene group or the like. A hydrogen atom in the group represented by Ar1 may be substituted by an alkyl group, aryl group or the like.

  一种聚合物化合物，包括由以下式（2）所表示的结构单元和由以下式（1）所表示的结构单元，其中R1表示烷基或类似基团，R2和R3各自独立地表示氢原子或类似基团，-Ar1-  （2），其中Ar1表示芳撑基团或类似基团。在由Ar1表示的基团中的氢原子可以被烷基、芳基或类似基团取代。