[Zn(spiro 5,5-dimethylcyclohexane 1,2,3-trione 2-phenylhydrazone(-H))2] | 1218922-32-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Zn(spiro 5,5-dimethylcyclohexane 1,2,3-trione 2-phenylhydrazone(-H))2]
• CAS: 1218922-32-7
• 化学式: C₂₈H₃₀N₄O₄Zn
• 分子量: 551.961
• InChiKey: OPQUZTNQGNZCLF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc(II) chloride 、 5,5-dimethyl-2-(2-phenylhydrazono)cyclohexane-1,3-dione 以 甲醇 为溶剂， 以50%的产率得到[Zn(spiro 5,5-dimethylcyclohexane 1,2,3-trione 2-phenylhydrazone(-H))2]
  参考文献：
  名称：

  Crystal Structure of Spiro 5,5-Dimethyl Cyclohexane1,2,3-trione 2-phenylhydrazone and Spectral Characterization of its Transition Metal Complexes

  摘要：

  The synthesis and characterization of spiro5,5-dimethylcyclohexane1,2,3-trione2-phenylhydrazone, phenylazodimedone (AD) and the characterization of its complexes with Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) have been carried out. AD was found to have the hydrazone form with intra-molecular N-HO hydrogen bond. The complexes were found to have a general formula ML2/ML3 when M is a divalent/trivalent metal, respectively, and L is the mono anion of AD. The structure of AD has been arrived at by various spectral techniques and the presence of hydrogen bonding has been verified by single crystal XRD. The complexes were characterized by elemental analyses, magnetic susceptibility measurements, electronic-infrared-1HNMR and mass spectral studies.

  DOI：

  10.1080/15533170903095011