trans-Diphenylbis(triphenylphosphan)platin(II) | 50988-66-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-Diphenylbis(triphenylphosphan)platin(II)
• 英文别名: benzene;platinum(2+);triphenylphosphane
• CAS: 50988-66-4；58073-72-6；79120-29-9
• 化学式: C₄₈H₄₀P₂Pt
• 分子量: 873.873
• InChiKey: GIEXGJFKZZPAFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cis-dichlorobis(triphenylphosphine)platinum(II) 在 magnesium 、 bromobenzene 作用下， 以 四氢呋喃 、 苯 为溶剂， 以34%的产率得到trans-Diphenylbis(triphenylphosphan)platin(II)
  参考文献：
  名称：

  Ertl, Josef; Debaerdemaeker, Tony; Brune, Hans Albert, Chemische Berichte, 1982, vol. 115, # 12, p. 3860 - 3874

  摘要：

  DOI：

文献信息

• Cationic phenyl and chloro-platinum(II) complexes with cyanamides and cyanoguanidine. X-ray structure of trans-[Pt(Ph)(NCNMe2)(PPh3)2][BPh4]
  作者：Cristina M.P. Ferreira、M.Fátima C. Guedes da Silva、Teresa Duarte、João J.R. Fraústo da Silva、Armando J.L. Pombeiro、Rino A. Michelin、Vadim Yu. Kukushkin

  DOI：10.1016/s0020-1693(02)00746-6

  日期：2002.5

  The phenyl-platinum(II) organocyanamide trans-[Pt(Ph)(NCNR2)(PPh3)(2)][BPh4] (R = Me la, Et 1b) or cyanoguanidine cis-[Pt(Ph)NCNC(NH2)(2)}(PPh3)(2)][BPh4] (2) complexes have been prepared by treatment of cis-[PtCl,(PPh3)(2)] in THF with NCNR, or NCNC(NH2)(2), respectively, in the presence of Na[BPh4], whereas the cyanoguanidine chloro-complex cis[PtClNCNC(NH2)(2)}(PPh3)(2)][BF4] (3) has been obtained by using Tl[BF4] instead of Na[BPh4]. Complex 3 reacts further with cyanoguanidine, in the presence of Na[BPh4], to produce the di(cyanoguanidine) cis-[PtNCNC(NH2)(2)}(2)(PPh3)(2)][BPh4](2) complex 5, whereas the amine complex cis-[PtCl(NH2R')(PPh3)(2)][BF4] (R' = CH2C6H4Me-4, 4) is formed on reaction of the former with NH2R' in CH2Cl2. The X-ray structure of la is also reported. (C) 2002 Elsevier Science B.V. All rights reserved.