3-烯丙基-4'-烯丙氧基-4-羟基二苯基砜 | 737795-84-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-烯丙基-4'-烯丙氧基-4-羟基二苯基砜
• 英文名称: 3-allyl-4-hydroxy-4'-allyloxydiphenyl sulfone
• 英文别名: 3-allyl-4'-allyloxy-4-hydroxydiphenyl sulfone；4-(4-Prop-2-enoxyphenyl)sulfonyl-2-prop-2-enylphenol
• CAS: 737795-84-5
• 化学式: C₁₈H₁₈O₄S
• 分子量: 330.405
• InChiKey: RNUDASTWVBCOTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  72
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,1'-砜基双[4-(2-丙烯)氧基苯] 在 1,10-菲罗啉 作用下， 反应 0.08h， 生成 3-allyl-4,4'-dihydroxydiphenyl sulfone 、 3-烯丙基-4'-烯丙氧基-4-羟基二苯基砜 、 5-(3-allyl-4-hydroxyphenylsulfonyl)-1-oxa-2-methylindane 、 4,4'-磺酰基双[2-(2-丙烯基)]苯酚
  参考文献：
  名称：

  EP1612205

  摘要：

  公开号：

文献信息

• THERMAL RECORDING MATERIAL AND NOVEL CRYSTAL OF BISPHENOL S DERIVATIVE
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP0913267A1

  公开（公告）日：1999-05-06

  A heat-sensitive recording material in which a heat-sensitive color-developing layer comprising, as the main components, a usually colorless or light-colored color former and a developer capable of developing the color former upon heating on a support, characterized by comprising, as the developer, crystals of 3,3'-diallyl-4,4'-dihydroxy-diphenyl sulfone which have DSC (Te) of at least 149°C and which are of a crystal form characterized by an X-ray diffraction pattern having peaks at least at diffraction angles (2θ) [°] of 7.2 and 22.0, obtained by an X-ray powder diffractometry using Cu-Kα rays. This heat-sensitive recording material is high in sensitivity, little in Discoloration of the ground in heat and moisture and excellent in image durability.

  一种热敏记录材料，其热敏显色层的主要成分包括通常为无色或浅色的显色剂和在支持物上加热后能使显色剂显色的显影剂，其特征在于包括、作为显影剂，3,3'-二烯丙基-4,4'-二羟基二苯砜的晶体，其 DSC（Te）至少为 149°C，其晶体形态的 X 射线衍射图的特征是至少在衍射角（2θ）[°]为 7.2 和 22.0 的 X 射线粉末衍射图。这种热敏记录材料灵敏度高，在高温和潮湿条件下地面变色小，图像耐久性好。
• METHOD FOR PRODUCING 3,3';-DIALLYL-4,4';-DIHYDROXYDIPHENYLSULFONE
  申请人：Sanko Chemical Industry Co., Ltd.

  公开号：EP1612205A1

  公开（公告）日：2006-01-04

  The present invention is characterized by subjecting 4,4'-diallyloxydiphenyl sulfone to a rearrangement reaction under microwave irradiation, preferably in molten state, to produce objective 3,3'-diallyl-4,4'-dihydroxydiphenyl sulfone efficiently in a short time, in high yield and in high purity. Further preferably, by carrying out said reaction in substantially oxygen-free atmosphere in the presence of at least one compound selected from a group consisting of an antioxidant, an organic basic compound and a chelate compound, the above-described object can be attained in more preferable manner.

  本发明的特点是在微波辐照下，优选在熔融状态下，使 4,4'-二烯丙基氧基二苯砜进行重排反应，以短时间、高产率和高纯度有效地生产客观的 3,3'-二烯丙基-4,4'-二羟基二苯砜。更优选的是，在至少一种选自抗氧化剂、有机碱性化合物和螯合物的化合物的存在下，在基本无氧的环境中进行上述反应，可以更理想地达到上述目的。
• Method for producing 3,3 diallyl-4,4 dihydroxydiphenylsulfone
  申请人：Enokida Hirotaka

  公开号：US20060217574A1

  公开（公告）日：2006-09-28

  The present invention is characterized by subjecting 4,4′-diallyloxydiphenyl sulfone to a rearrangement reaction under microwave irradiation, preferably in molten state, to produce objective 3,3′-diallyl-4,4′-dihydroxydiphenyl sulfone efficiently in a short time, in high yield and in high purity. Further preferably, by carrying out said reaction in substantially oxygen-free atmosphere in the presence of at least one compound selected from a group consisting of an antioxidant, an organic basic compound and a chelate compound, the above-described object can be attained in more preferable manner.

  本发明的特点是在微波辐照下，最好是在熔融状态下，使4,4′-二烯丙基氧基二苯砜进行重排反应，从而在短时间内高效率、高产率和高纯度地生产出客观存在的3,3′-二烯丙基-4,4′-二羟基二苯砜。进一步优选的是，在至少一种选自抗氧化剂、有机碱性化合物和螯合物的化合物存在下，在基本无氧的气氛中进行上述反应，可以更理想地达到上述目的。
• JPS6253957A
  申请人：——

  公开号：JPS6253957A

  公开（公告）日：1987-03-09
• US6114282A
  申请人：——

  公开号：US6114282A

  公开（公告）日：2000-09-05