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bis(5-bromosalicylaldehydato)diaquozinc(II) | 532382-76-6

中文名称
——
中文别名
——
英文名称
bis(5-bromosalicylaldehydato)diaquozinc(II)
英文别名
[Zn(Brsal)2(H2O)2];zinc;5-bromo-2-formylphenolate;dihydrate
bis(5-bromosalicylaldehydato)diaquozinc(II)化学式
CAS
532382-76-6
化学式
C14H12Br2O6Zn
mdl
——
分子量
501.444
InChiKey
PTAKOVXVSHVYLJ-UHFFFAOYSA-L
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    None
  • 重原子数:
    None
  • 可旋转键数:
    None
  • 环数:
    None
  • sp3杂化的碳原子比例:
    None
  • 拓扑面积:
    None
  • 氢给体数:
    None
  • 氢受体数:
    None

反应信息

  • 作为反应物:
    描述:
    bis(5-bromosalicylaldehydato)diaquozinc(II)bis(acetophenone)ethylenediamine乙醇 为溶剂, 以83.6%的产率得到bis(5-bromosalicylaldehydato)(bis(acetophenone)ethylenediamine)zinc(II) monohydrate
    参考文献:
    名称:
    Synthesis, Spectral, and Biocidal Studies of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Mixed‐Ligand Complexes
    摘要:
    Complexes of transition metals with salicylaldehyde (saIH) or 5-bromosalicylaldehyde (Br-salH) in I : 2 molar ratio, have the compositions [M(H2O)(2)(sal)(2)] . H2O (1) or [M(H2O)(2)(Br-sal)(2)] . H2O (2), respectively. The Schiff base derived from ethylenediamine and acetophenone in I : I molar ratio in alcoholic solution yields his(acetophenone)ethylenediamine (acphen). Further reaction of (1) or (2) with acphen in alcohol yielded mixed-ligand complexes of the type [M(sal)(2)acphen] or [M(Br-sal)(2) acphen], respectively. All of these complexes are Soluble in ethanol and methanol. They were characterized on the basis of elemental analyses, magnetic measurements, infrared spectra, electronic spectra, and thermogravimetric analyses. All of these complexes have been screened for their antimicrobial activity against bacteria] strands using the agar diffusion method.
    DOI:
    10.1081/sim-120037513
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