| 105011-43-6

• CAS: 105011-43-6
• 化学式: C₂₆H₂₅IMoNO₃PS₂
• 分子量: 717.44
• InChiKey: PNYHJWZSOIMEIN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  MoI2(CO)3(MeCN)2 、 sodium diethyldithiocarbamate trihydrate 在 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Reactions of the seven-co-ordinate complexes [MI2(CO)3(NCMe)2] and [MI2(CO)3(NCMe)L](M = Mo or W; L = PPh3, AsPh3 or SbPh3) with dithiocarbamate ligands

  摘要：

  The complexes [MI2(CO)3(NCMe)2] (M = Mo or W) react with 1 equivalent of Na[S2CN(CH2Ph)2] eventually to give the iodo-bridged dimers [{M(mu-I)(CO)3[S2CN(CH2Ph)2]}2]. The reaction of [MI2(CO)3(NCMe)2] with 1 equivalent of L (L = PPh3, AsPh3 or SbPh3) gave [MI2(CO)3(NCMe)L] which when treated in situ with Na[S2CNR2] (R = Me, Et or CH2Ph) afforded [MI(CO)3L(S2CNR2)]. The complexes [MoI(CO)3L(S2CNR2)] prepared as described above when treated in situ with 1 equivalent of [S2CNR2]- generally give the mixed-ligand oxides [Mo2O3(S2CNR2)2(S2CNR'2)2]. The complexes [WI(CO)3(PPh3)(S2CNR2)] (R = Me, Et or CH2Ph) when treated in situ with Na[S2CNR'2] afforded [W(CO)2(PPh3)(S2CNR2)(S2CNR'2)] (R = Me, R' = Et; R = Me, R' = CH2Ph; R = Et, R' = CH2Ph), whereas reaction with the AsPh3 and SbPh3 complexes in an analogous manner gave [W(CO)3(S2CNR2)(S2CNR'2)] in low yield. Reaction of [MoI2(CO)3(NCMe)2] with 2 equivalents of Na[S2CNEt2].3H2O gave the previously reported oxide compound [Mo2O3(S2CNEt2)4], whereas [WI2(CO)3(NCMe)2] reacts to give [W(CO)3(S2CNEt2)2]. Two equivalents of Na[S2CN(CH2Ph)2] react with [MoI2(CO)3(NCMe)L] to give for L = PPh3 and AsPh3 the oxides [Mo2O3{S2CN(CH2Ph)2}4] and the seven-co-ordinate complex [Mo(CO)2(SbPh3){S2CN(CH2Ph)2}2] for L = SbPh3. The complexes [W(CO)2L{S2CN(CH2Ph)2}2] (L = PPh3, AsPh3 or SbPh3) were prepared in an analogous manner. Low-temperature C-13 NMR spectra are interpreted to suggest the likely stereochemistry of several of these complexes.

  DOI：

  10.1039/dt9910000131