[Mn(hexafluoroacetylacetonate)2(N-(4-pyridylmethyl)imidazole)] | 186311-00-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Mn(hexafluoroacetylacetonate)2(N-(4-pyridylmethyl)imidazole)]
• CAS: 186311-00-2
• 化学式: C₁₉H₁₁F₁₂MnN₃O₄
• 分子量: 628.233
• InChiKey: YAMFUBACOBYDRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-咪唑-1-基甲基-吡啶 、 bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionate)manganese(II) dihydrate 以 甲醇 、 乙醚 为溶剂， 生成 [Mn(hexafluoroacetylacetonate)2(N-(4-pyridylmethyl)imidazole)]
  参考文献：
  名称：

  One-dimensional structures of manganese(II) complexes [MnII(hfac)2L] hfac = hexafluoroacetylacetonate anion; L = N-(4-pyridylmethyl)imidazole, trans-1,2-bis(4-pyridyl)ethylene, imidazole)

  摘要：

  Bis(hexafluoroacetylacetonato)diaquamanganese(II)[Mn(hfac)(2)(H2O)(2)] reacts with N-(4-pyridylmethyl)imidazole (pyrim), trans-1,2-bis(4-pyridyl)ethylene (bpye) and imidazole (Him) to give their adducts with three different kinds of one-dimensional structures [Mn(hfac)(2)(pyim)] (1), [Mn(hfac)(2)(bpye)] (2) and [Mn(hfac)(2)(Him)(2)] (3), respectively. Compound 1 crystallizes in the monoclinic space group P2(1)/n with a=9.696(3), b=14.839(4), c=17.076(3) Angstrom, beta=92.70(2)degrees, and assumes a one-dimensional structure running along the b-axis in which the adjacent molecules are related by a two-fold screw axis. Compound 2 crystallizes in the space group C2/c with a=9.554(2), b=16.476(2), c=16.137(2) Angstrom, beta=96.97(2)degrees, and assumes a zigzag-chain structure. Compound 3 crystallizes in the space group P2(1)/c with a=7.526(3), b=14.506(3), c=10.394(2) Angstrom, beta=96.71(2)degrees and the one-dimensional structure of 3 is formed by a hydrogen bond between NH of imidazole and O of hfac.

  DOI：

  10.1016/s0020-1693(96)05115-8