N-[cyclopenta-1,3-dien-1-yl(dimethyl)silyl]-4-methylpyridin-2-amine;iron(2+) | 188288-44-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-[cyclopenta-1,3-dien-1-yl(dimethyl)silyl]-4-methylpyridin-2-amine;iron(2+)
• CAS: 188288-44-0
• 化学式: C₂₆H₃₄FeN₄Si₂
• 分子量: 514.601
• InChiKey: SGQDISVDCPZWPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (Me2N)3TiCl 、 N-[cyclopenta-1,3-dien-1-yl(dimethyl)silyl]-4-methylpyridin-2-amine;iron(2+) 以 正己烷 为溶剂， 以48%的产率得到chlorotitanium(3+);[cyclopenta-1,3-dien-1-yl(dimethyl)silyl]-(4-methylpyridin-2-yl)azanide;dimethylazanide;iron(2+)
  参考文献：
  名称：

  Ferrocene Based Amido �Ligands�; Synthesis of bimetallic bis(aminopyridinato) titanium complexes

  摘要：

  AbstractThe ferrocene based aminopyridine “ligand” fc(Me2SiApH)2 (3), fc(Me2SiApH)2 = 1,1′‐bis{[(N‐4‐methylpyridin‐2‐yl)amino]dimethylsilyl}ferrocene, has been synthesized by the reaction of 1,1′‐bis(chlorodimethylsilyl)ferrocene (1) with the sodium salt of 4‐methyl‐2‐aminopyridine in hexane. Compound 1 is accessible by the reaction of 1,1′‐dilithioferrocene with a fortyfold excess of Me2SiCl2. The reactions of 3 with one equiv of Ti(NMe2)4 or ClTi(NMe2)3, resp. afford the corresponding bimetallic titanium complexes fc(Me2SiAp)2Ti(NMe2)2 (4) or fc(Me2SiAp)2Ti(NMe2Cl (5)), resp. The crystal structure of 3 is reported.

  DOI：

  10.1002/zaac.19976230162
• 作为产物：
  描述：

  (1,1'-ferrocenediyl)dimethylsilane 、 1,1'-bis(chlorodimethylsilyl)ferrocene 、 sodium 4-picoline-2-ylamide 以 正己烷 为溶剂， 以39%的产率得到N-[cyclopenta-1,3-dien-1-yl(dimethyl)silyl]-4-methylpyridin-2-amine;iron(2+)
  参考文献：
  名称：

  Ferrocene Based Amido �Ligands�; Synthesis of bimetallic bis(aminopyridinato) titanium complexes

  摘要：

  AbstractThe ferrocene based aminopyridine “ligand” fc(Me2SiApH)2 (3), fc(Me2SiApH)2 = 1,1′‐bis{[(N‐4‐methylpyridin‐2‐yl)amino]dimethylsilyl}ferrocene, has been synthesized by the reaction of 1,1′‐bis(chlorodimethylsilyl)ferrocene (1) with the sodium salt of 4‐methyl‐2‐aminopyridine in hexane. Compound 1 is accessible by the reaction of 1,1′‐dilithioferrocene with a fortyfold excess of Me2SiCl2. The reactions of 3 with one equiv of Ti(NMe2)4 or ClTi(NMe2)3, resp. afford the corresponding bimetallic titanium complexes fc(Me2SiAp)2Ti(NMe2)2 (4) or fc(Me2SiAp)2Ti(NMe2Cl (5)), resp. The crystal structure of 3 is reported.

  DOI：

  10.1002/zaac.19976230162