1-(3-iodopropyl)-1-methylpyrrolidin-1-ium iodide | 19653-46-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 1-(3-iodopropyl)-1-methylpyrrolidin-1-ium iodide
• CAS: 19653-46-4
• 化学式: C₈H₁₇IN*I
• 分子量: 381.039
• InChiKey: UATPEGXPDLZNFK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.94
• 重原子数：
  11.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  4,7-二氯喹啉 、 1-(3-iodopropyl)-1-methylpyrrolidin-1-ium iodide 反应 0.01h， 生成
  参考文献：
  名称：

  Monomeric asymmetric two- and three-cationic monomethine cyanine dyes as novel photoinitiators for free-radical polymerization

  摘要：

  Several two- and three-cationic monomethine cyanine dyes, possessing a benzothiazolium moiety were synthesized and evaluated as initiators of the free radical polymerization of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate under visible light. Dyes bearing 1-methylpyrrolidinium, 4-methylmorpholinium, pyridinium and 3-(N,N-dimethylamino)propan-1-ol substituents were useful initiators. All derivatives absorbed in the region 510-570 nm and displayed molar absorption coefficients of 40 000-60 000 dm(3) mol(-1) cm(-1). A kinetic study of photoinitiated polymerization performed with the use of the electron donor n-butyltriphenylborate salt showed that the dyes were efficient two-component photoinitiators. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2009.12.007
• 作为产物：
  描述：

  1-甲基吡咯烷 、 1,3-二碘丙烷 以 丙酮 为溶剂， 反应 168.0h， 生成 1-(3-iodopropyl)-1-methylpyrrolidin-1-ium iodide
  参考文献：
  名称：

  Monomeric asymmetric two- and three-cationic monomethine cyanine dyes as novel photoinitiators for free-radical polymerization

  摘要：

  Several two- and three-cationic monomethine cyanine dyes, possessing a benzothiazolium moiety were synthesized and evaluated as initiators of the free radical polymerization of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate under visible light. Dyes bearing 1-methylpyrrolidinium, 4-methylmorpholinium, pyridinium and 3-(N,N-dimethylamino)propan-1-ol substituents were useful initiators. All derivatives absorbed in the region 510-570 nm and displayed molar absorption coefficients of 40 000-60 000 dm(3) mol(-1) cm(-1). A kinetic study of photoinitiated polymerization performed with the use of the electron donor n-butyltriphenylborate salt showed that the dyes were efficient two-component photoinitiators. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2009.12.007