[Au2I2(μ-1,1'-bis(diphenylphosphino)ferrocene)] | 196490-30-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Au2I2(μ-1,1'-bis(diphenylphosphino)ferrocene)]
• 英文别名: cyclopenta-2,4-dien-1-yl(diphenyl)phosphane;iodogold;iron(2+)
• CAS: 196490-30-9
• 化学式: C₃₄H₂₈Au₂FeI₂P₂
• 分子量: 1202.13
• InChiKey: TUHYDWCOMBZUNL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1,1'-双(二苯基膦)二茂铁)二氯化二金 、 potassium iodide 以 丙酮 为溶剂， 以60%的产率得到[Au2I2(μ-1,1'-bis(diphenylphosphino)ferrocene)]
  参考文献：
  名称：

  Substitution Reaction Studies on [Au₂Cl₂(μ-dppf)] (dppf = 1,1‘-Bis(diphenylphosphino)ferrocene). Synthesis of the First Gold(I) Complex with a μ₃-2-Pyridinethiolate Ligand

  摘要：

  Substitution of the chlorine ligand in the complex [Au2Cl2(mu-dppf)] by other halogens or anionic Ligands such as Spy(-)(2-pyridinethiolate) or S2CNR2- have been carried out. The complexes [Au-2(Spy)(2)(mu-dppf)] and [Au-2(S2CNR2)(2)(mu-dppf)] possess a nitrogen or sulfur donor atom that can coordinate to a metallic fragment; thus reactions of these complexes with [Au(OTf)(PR3)] in various molar ratios have been studied. The crystal structures of [Au2I2(mu-dppf)], [Au2Cl2(mu-dppf)], and [Au-3(mu(3)-Spy)(mu-dppf)(PPh2Me)](OTf)(2) have been established by X-ray diffraction studies. The last represents the first example where a pyridinethiolate ligand bridges three gold atoms.

  DOI：

  10.1021/ic9704445