α,α'-Bis-(4-aminocyclohexyl)-p-diisopropylbenzol | 60469-07-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α,α'-Bis-(4-aminocyclohexyl)-p-diisopropylbenzol
• 英文别名: 4-[2-[4-[2-(4-Aminocyclohexyl)propan-2-yl]phenyl]propan-2-yl]cyclohexan-1-amine
• CAS: 60469-07-0
• 化学式: C₂₄H₄₀N₂
• 分子量: 356.595
• InChiKey: KDPWXIAIQACXIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• AROMATIC POLYAMIDES AND AGENTS FOR IMPARTING GAS BARRIER PROPERTIES TO THEM
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0280736A1

  公开（公告）日：1988-09-07

  Aromatic polyamldes excellent in melt moldability and having good heat resistance, mechanical strength, transparency and excellent gas barrier properties. The aromatic polyamides can be used as the material for containers because of their excellent gas barrier properties, and can protect a product contained therein from a gas.

  芳香族聚酰胺具有优异的熔融模塑性、良好的耐热性、机械强度、透明度和优异的气体阻隔性。由于芳香族聚酰胺具有优异的气体阻隔性，因此可用作容器材料，保护容器中的产品不受气体影响。
• Polyamide resin compositions and laminates thereof
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0325030A2

  公开（公告）日：1989-07-26

  A polyamide resin composition which comprises: (A) a random polyamide comprising (a) at least one isphthaloyl diamine component represented by the general formula (I) of wherein R⁰ represents a divalent hydrocarbon group of 4-25 carbons, in a total amount of 50-100 mole %; and (b) at least one diacyloyl diamine component represented by the general formula (II) of -[NH-R⁰-NHCO-Ar-CO)- wherein R⁰ is as defined above and Ar represents a divalent aromatic hydrocarbon group of 6-20 carbons but is not a 1,3-phenylene group, in a total amount of 50-0 mole %, and (B) a polyamide comprising: (c) at least one diamine component of 4-25 carbons or dicarboxylic acid component of 4-20 carbons which have no aromatic nuclei; or (d) at least one aminocarboxylic acid component; or (e) at least one diamine component of 4-25 carbonss,dicarboxylic acid component of 4-20 carbons which has no aromatic nuclei, or aminocarboxylic acid component. The composition has high impermeability and a low glass transition temperature and may be used to manufacture laminates and moulded articles.

  一种聚酰胺树脂组合物，包括 (A) 无规聚酰胺，包括 (a) 至少一种由以下通式(I)代表的间苯二甲酰二胺组分 其中 R⁰ 代表 4-25 个碳原子的二价烃基，总量为 50-100 摩尔 %；以及 (b) 至少一种由通式 (II) 表示的二乙酰基二胺组分，其总用量为 50-100 摩尔 %；以及 -NH-R⁰-NHCO-Ar-CO)- 其中 R⁰ 如上定义，Ar 代表 6-20 个碳原子的二价芳香烃基团，但不是 1，3-亚苯基基团，总量为 50-0 摩尔 %，以及 (B) 聚酰胺，包括 (c) 至少一种不含芳香族核的 4-25 碳原子的二胺组分或 4-20 碳原子的二 羧酸组分；或 (d) 至少一种氨基甲酸酯组分；或 (e) 至少一种含 4-25 个碳原子的二胺组分s 、含 4-20 个碳原子的不含芳香族核 的二羧酸组分或氨基羧酸组分。 这种组合物具有较高的抗渗性和较低的玻璃化转变温度，可用于制造层压板和模制件。
• Polyamide resin compositions
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0360611A2

  公开（公告）日：1990-03-28

  A polyamide resin composition which comprises: (A) an aromatic polyamide resin comprising a dicarboxylic acid component comprising an aromatic dicarboxylic acid and a diamine component comprising at least one aliphatic diamine or alicyclic diamine; (B) a fibrous reinforcement; and (C) at least one additive which is a group I, II or III metal salt of a higher fatty acid or an acid ester, partially saponified ester or metal salt of an aliphatic carboxylic acid of 26-32 carbons. The resin composition has high fluidity and mold-releasing properties as well as high heat resistance and rigidity, and can be molded without decomposition of the resin.

  一种聚酰胺树脂组合物，包括：(A)芳香族聚酰胺树脂，其二羧酸组分包括芳香族二 羧酸和二胺组分，二胺组分包括至少一种脂肪族二胺或脂环族二胺；(B)纤维增强剂； 以及(C)至少一种添加剂，添加剂为高级脂肪酸的 I、II 或 III 族金属盐或 26-32 碳原子数的脂 肪族羧酸的酸酯、部分皂化酯或金属盐。 这种树脂组合物具有很高的流动性和脱模性，以及很高的耐热性和刚性，可以在树脂不分解的情况下进行模塑。
• Polyamide and polyamide resin composition
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0449466A1

  公开（公告）日：1991-10-02

  An aromatic polyamide having a specific intrinsic viscosity comprises dicarboxylic acid recurring units derivable from terephthalic acid and an aliphatic dicarboxylic acid in specified proportions, and diamine recurring units derivable from an aliphatic alkylenediamine and/or alicyclic alkylenediamine. Polyamide resin compositions containing the aromatic polyamide and a filler are also disclosed.

  一种具有特定固有粘度的芳香族聚酰胺包含按特定比例衍生自对苯二甲酸和脂肪族二羧酸的二羧酸循环单元，以及衍生自脂肪族烷基二胺和/或脂环族烷基二胺的二胺循环单元。此外，还公开了含有芳香族聚酰胺和填料的聚酰胺树脂组合物。
• Production of aromatic polyamide
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0744431A2

  公开（公告）日：1996-11-27

  A process for producing an aromatic polyamide which comprises: (a) a dicarboxylic acid component which consists of 30-100 mol% of terephthalic acid and optionally 0-70 mol% of at least one dicarboxylic acid other than terephthalic acid, and (b) a diamine component which consists of 50-100 mol% of an aliphatic alkylenediamine of 4-25 carbons and optionally 0-50 mol% of at least one alicyclic diamine of 3-25 carbons, said process comprising a first step of performing melt reaction of said dicarboxylic acid with said diamine, thereby giving a low molecular weight condensate having an intrinsic viscosity [η] of 0.05-0.6 dl/g, a second step of subjecting it to solid phase polymerization, thereby giving an aromatic polyamide precursor having an intrinsic viscosity [η] of 0.5-1.0 dl/g, and a third step of subjecting it to melt polymerization, thereby giving an aromatic polyamide having a desired intrinsic viscosity [η] of 0.8-2.5 dl/g. This process permits the industrial production of high molecular weight aromatic polyamides in an economical and efficient manner.

  一种生产芳香族聚酰胺的工艺，包括 (a) 二羧酸组分，其中对苯二甲酸占 30-100 摩尔%，可选对苯二甲酸以外的 至少一种二羧酸占 0-70 摩尔%，以及 (b) 二胺组分，由 50-100 摩尔%的 4-25 碳原子的脂肪族烷基二胺和可选的 0-50 摩尔%的至少一种 3-25 碳原子的脂环族二胺组成，所述工艺包括第一步，将所述二羧酸与所述二胺进行熔融反应，从而得到低分子量缩合物，其固有粘度[η]为 0.05-0.6 dl/g，第二步进行固相聚合，得到本征粘度[η]为 0.5-1.0 dl/g的芳香族聚酰胺前体，第三步进行熔融聚合，得到本征粘度[η]为 0.8-2.5 dl/g的芳香族聚酰胺。 这种工艺可以经济高效地工业化生产高分子量的芳香族聚酰胺。