(O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnCr(CO)5 | 216981-09-8

• 英文名称: (O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnCr(CO)5
• CAS: 216981-09-8
• 化学式: C₃₅H₅₂CrN₆O₇Sn
• 分子量: 839.54
• InChiKey: VUYKWZYETPBCTR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis[2,4,6-tris(dimethylaminomethyl)phenoxy]-stannylene 、 六羰基铬 在 四氢呋喃 作用下， 以 四氢呋喃 为溶剂， 以88%的产率得到(O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnCr(CO)5
  参考文献：
  名称：

  Low coordinate germanium and tin compounds (ArO)2ME and (ArO)2MM′Ln M=Ge, Sn; E=S, Se, –NSiMe3 M′=Cr, W, Fe, Pt [Ar=2,4,6-tris((dimethylamino)methyl)phenyl-]

  摘要：

  The reactions of the divalent species (ArO)(2)M (Ar = 2,4,6-[(CH3)(2)NCH2](3)C6H2; M = Ge, Sn) with either Me3SiN3, elemental S-8, Se or transition metal complexes M'(CO)(n + 1) (M' = Fe, n = 4; M' = Cr, W; n = 5) (Ph3P)(2)Pt . C2H4 have resulted in the isolation of either the new stable formal metallanimines (ArO)(2)M=N-SiMe3, germanethione, -selone (ArO)(2)Ge=E (E = S, Se) (the expected formations of the stannanethione and -selone were not observed), or the (ArO)(2)M=M'(CO)(n), (ArO)(2)M=Pt(PPh3)(2) complexes, respectively. The direct oxidation of the (ArO)(2)M species with various oxidizing agents led to the formation of the corresponding metalloxanes [(ArO)(2)M-O-](2). All of the chalcogenido- and transition metal-metal 14 complexes have been physicochemically and chemically characterized. The reactions of the (ArO)(2)Ge=E (E = S, Se) compounds with 3,5-di-tert-butyl-1,2-benzoquinone produced, by extrusion of sulfur or selenium, the dioxametalloles corresponding to the formal addition of the divalent species (ArO)(2)M to the benzoquinone. A substitution reaction of chalcogen (S/Se) has been observed permitting to go from germaneselone to germanethione. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00743-8