CpRu(bis(diphenylphosphino)methane)S(5-methyl-1,3,5-thiadiazolyl) | 1257344-49-2

• 英文名称: CpRu(bis(diphenylphosphino)methane)S(5-methyl-1,3,5-thiadiazolyl)
• CAS: 1257344-49-2
• 化学式: C₃₃H₃₀N₂P₂RuS₂
• 分子量: 681.764
• InChiKey: UYJDMFGHLFPIGX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(三苯基膦)环戊二烯基氯化钌(II) 、 2-巯基-5-甲基-1,3,4-噻二唑 、 双二苯基膦甲烷 在 methyllithium 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 以60%的产率得到CpRu(bis(diphenylphosphino)methane)S(5-methyl-1,3,5-thiadiazolyl)
  参考文献：
  名称：

  Synthesis of cyclopentadienyl ruthenium complexes containing 5-membered N-heterocyclic thiolates

  摘要：

  Mononuclear ruthenium-thiolate complexes of structural type CpRu(PPh3)(2)SR (1) [R = 2-imidazolyl (a), 1-methylimidazolyl (b), 5-methyl-1,3,5-thiadiazolyl (c) and 5-methyl-4H-1,2,4-triazolyl (d)] are accessible from the reaction of CpRu(PPh3)(2)Cl with the corresponding thiolate anions. Reaction of CpRu(PPh3)(2)Cl with the heterocyclic-thiolate anions in the presence of the bisphosphine ligands affords CpRu(P-P) SR [P-P = bis(diphenylphosphino) methane; dppm (2), bis(diphenylphosphino) ethane; dppe (3)]. If CO gas was bubbled through a THF solution of 1b, the complex CpRu(PPh3)(CO)S(C4N2H5) (4b) is produced. These ruthenium-heterocyclic thiolate complexes have been characterized by elemental analysis, spectroscopy (IR, H-1, P-31{H-1} NMR and MS) and cyclic voltammetry for some samples. The solid-state structures of 3a and 3b are determined by single-crystal X-ray structure analysis. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.05.022