Hg(diacetyl-2-(4-methyl-3-thiosemicarbazonato)-3-(2-hydrazonatopyridine)(H2O) | 1360468-31-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Hg(diacetyl-2-(4-methyl-3-thiosemicarbazonato)-3-(2-hydrazonatopyridine)(H2O)
• CAS: 1360468-31-0
• 化学式: C₁₁H₁₆HgN₆OS
• 分子量: 480.944
• InChiKey: NQGGPPSSPTUDBV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  mercuric(II) nitrate monohydrate 、 diacetyl-2-(4-methyl-3-thiosemicarbazone)-3-(2-hydrazonepyridine) 在 LiOH*H₂O 作用下， 以 甲醇 为溶剂， 以55%的产率得到Hg(diacetyl-2-(4-methyl-3-thiosemicarbazonato)-3-(2-hydrazonatopyridine)(H2O)
  参考文献：
  名称：

  Complexes of group 12 metals containing a hybrid thiosemicarbazone-pyridylhydrazone ligand

  摘要：

  The reaction of diacetyl-2-(4-methyl-3-thiosemicarbazone) with 2-hydrazinopyridine leads to the formation of two products, LH2 and [LH3]Cl depending on the amount of HCl present in the reaction mixture. The reactivity of these molecules towards zinc(II), cadmium(II) and mercury(II) nitrates has been investigated under different reaction conditions. The new complexes have been fully characterized by Cd-113 and Hg-199 NMR, as well as C-13 and Cd-113 CP/MAS NMR and by X-ray diffraction. All the complexes have the same 1: 1 ligand to metal ratio, but the protonation state of the ligand depends on the reaction conditions, from neutral to double deprotonated. The coordination numbers in the complexes depend on the metal preferences leading to the formation of complexes with different structural characteristics. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.10.023